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Merck

136131

Sigma-Aldrich

1,2-二甲基咪唑

97%

别名:

1,2-Dimethyl-1H-imidazole, 1,2DMZ

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About This Item

经验公式(希尔记法):
C5H8N2
CAS号:
分子量:
96.13
EC號碼:
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22

蒸汽壓力

1 mmHg ( 20 °C)

化驗

97%

形狀

solid

自燃溫度

896 °F

bp

204 °C (lit.)

mp

37-39 °C (lit.)

密度

1.084 g/mL at 25 °C (lit.)

SMILES 字串

Cc1nccn1C

InChI

1S/C5H8N2/c1-5-6-3-4-7(5)2/h3-4H,1-2H3

InChI 密鑰

GIWQSPITLQVMSG-UHFFFAOYSA-N

一般說明

1,2-二甲基咪唑与四乙酸铜 (II) 反应生成 顺式 -(乙酸酯)(1,2-二甲基咪唑)铜 (II) 络合物 。它与溴苄发生缅舒特金反应生成 3-苄基-1,2-二甲基咪唑溴化物,并在各种离子液体和分子有机溶剂中研究了反应动力学

應用

1,2-二甲基咪唑用于合成 1,2-二甲基-3- n -丁基咪唑氯化物和 1,2-二甲基-3- n -丙基咪唑氯化物 。它也用于合成 1-(2-甲氧基乙基)-2,3-二甲基咪唑氯化物和六氟磷酸盐

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

197.6 °F - closed cup

閃點(°C)

92 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Alain Lesimple et al.
Journal of mass spectrometry : JMS, 43(1), 35-41 (2007-07-10)
A number of 1,2-dimethylimidazole ionic liquids substituted on N(II) with alkyl chains of varying lengths terminated with sulfur-containing groups were investigated by electrospray high-resolution tandem Fourier-transform mass spectrometry. Fragmentation pathways are strongly dependent on the oxidation state of the sulfur
M M Fitzgerald et al.
Protein science : a publication of the Protein Society, 4(9), 1844-1850 (1995-09-01)
The activated state of cytochrome c peroxidase, compound ES, contains a cation radical on the Trp-191 side chain. We recently reported that replacing this tryptophan with glycine creates a buried cavity at the active site that contains ordered solvent and
Wesley A Henderson et al.
Chemical communications (Cambridge, England), (35)(35), 3708-3710 (2006-10-19)
The crystal structures and thermal behavior of the 1-(2-methoxyethyl)-2,3-dimethylimidazolium chloride and hexa-fluorophosphate salts are compared with the analogous 1-butyl-2,3-dimethylimidazolium salts to examine the influence of the ether oxygen on salt thermal properties for a typical constituent cation used in the
The coordination environment of mitochondrial cytochromes b.
K R Carter et al.
FEBS letters, 132(2), 243-246 (1981-09-28)
Physical properties of substituted imidazolium based ionic liquids gel electrolytes.
Sutto TE, et al.
Zeitschrift fur Naturforschung, A, 57(11), 839-846 (2002)

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