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品質等級
化驗
≥99%
折射率
n20/D 1.445 (lit.)
bp
152 °C (lit.)
密度
0.837 g/mL at 25 °C (lit.)
SMILES 字串
CC1(C)CCCC(C)(C)N1
InChI
1S/C9H19N/c1-8(2)6-5-7-9(3,4)10-8/h10H,5-7H2,1-4H3
InChI 密鑰
RKMGAJGJIURJSJ-UHFFFAOYSA-N
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一般說明
2,2,6,6-四甲基哌啶是一种位阻仲胺，用于制备金属-酰胺碱(metallo-amide bases)和选择性制备硅基取代的烯酮缩酮(silyl ketene acetals)。
應用
2,2,6,6-四甲基哌啶可用作反应剂，用于：
- 通过烯丙基氯类的烯丙基胺化合成烯丙化叔胺。
- 以Oxone为氧化剂，通过氧化反应合成羟胺。
- 以碘为氧化剂，与杂环硫醇反应合成次磺酰胺化合物。
- 与CO2和苯基硅烷经N-甲基化反应合成N-甲基化胺。
- 与醛和炔通过三组分Mannich偶联反应合成炔丙胺化合物。
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Met. Corr. 1 - Skin Corr. 1A - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 2
閃點（°F）
98.6 °F - closed cup
閃點（°C）
37 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
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The Journal of organic chemistry, 83(21), 13498-13506 (2018-10-23)
The reaction pathways of lithium 2,2,6,6-tetramethylpiperidide (LiTMP)-mediated deprotonative metalation of methoxy-substituted arenes were investigated. Importantly, it was experimentally observed that, whereas TMEDA has no effect on the course of the reactions, the presence of more than the stoichiometric amount of
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