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Merck
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文件

100331

Sigma-Aldrich

氯甲基甲醚

technical grade

别名:

MOM chloride, 氯甲氧基甲烷, 甲基氯甲醚

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About This Item

线性分子式:
ClCH2OCH3
CAS号:
107-30-2
分子量:
80.51
EC號碼:
203-480-1
MDL號碼:
MFCD00000885
分類程式碼代碼:
12352101
PubChem物質ID:
24846524
NACRES:
NA.22

等級

technical grade

蒸汽壓力

3.55 psi ( 20 °C)

折射率

n20/D 1.396 (lit.)

bp

55-57 °C (lit.)

密度

1.06 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

COCCl

InChI

1S/C2H5ClO/c1-4-2-3/h2H2,1H3

InChI 密鑰

XJUZRXYOEPSWMB-UHFFFAOYSA-N

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相关类别

應用

Chloromethyl methyl ether (MOM-Cl) can be used as a reagent:
  •  For the introduction of the methoxymethyl (MOM) protecting group by converting alcohols to methoxy methyl (MOM) ethers.
  •  To prepare some methoxymethyl group containing metal complexes coordinated to carbonyl and dipyridyl ligands.        
  • In the preparation of fluorene/chloromethyl methyl ether cross-linked polymers by Friedel-Crafts polymerization.

訊號詞

Danger

危險分類

Acute Tox. 1 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1A - Flam. Liq. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

60.8 °F - closed cup

閃點（°C）

16 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves

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Jung-Jae Lee et al.
Chemical communications (Cambridge, England), (15)(15), 1962-1963 (2009-04-01)
N-Alkylation of a fluorescent macrocyclic amine in aqueous micellar solution produces enhanced emission; the reaction with chloromethyl methyl ether exhibits autocatalysis.
Bis(Chloromethyl) ether and technical-grade chloromethyl methyl ether.
Report on carcinogens : carcinogen profiles, 11, III56-III57 (2004-01-01)
Organometallics, 25, 4909-4909 (2006)
A Blair et al.
Cancer causes & control : CCC, 8(3), 473-490 (1997-05-01)
Epidemiologic evidence on the relation between reactive chemicals and cancer is reviewed. These highly reactive chemicals (acrylonitrile; bis[chloromethyl]ether and chloromethyl methyl ether; 1,3-butadiene, ethylene oxide; formaldehyde; mustard gas; sulfuric acid; and vinyl chloride) vary in use and exposure. All are
A modified low-cost preparation of chloromethyl methyl ether (MOM-Cl)
Reggelin M and Doerr S
Synlett, 2004(06), 1117-1117 (2004)
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