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Key Documents

51269

Sigma-Aldrich

Dihydroxyacetone phosphate hemimagnesium salt hydrate

≥95% (TLC)

Synonyme(s) :

1,3-Dihydroxy-2-propanone 1-phosphate disodium salt, 1-Hydroxy-3-(phosphonooxy)-2-propanone disodium salt, DHAP Na2

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About This Item

Formule empirique (notation de Hill):
C3H5Mg0.5O6P · xH2O
Numéro CAS:
Poids moléculaire :
180.19 (anhydrous basis)
Code UNSPSC :
12352107
ID de substance PubChem :
Nomenclature NACRES :
NA.25

Niveau de qualité

Pureté

≥95% (TLC)

Température de stockage

−20°C

Chaîne SMILES 

O.OCC(=O)COP(O)(=O)O[Mg]OP(O)(=O)OCC(=O)CO

InChI

1S/2C3H7O6P.Mg.H2O/c2*4-1-3(5)2-9-10(6,7)8;;/h2*4H,1-2H2,(H2,6,7,8);;1H2/q;;+2;/p-2

Clé InChI

XIBMKSGIYJARCI-UHFFFAOYSA-L

Application

Dihydroxyacetone phosphate hemimagnesium salt hydrate (DHAP Mg) is a magnesium salt of DHAP. DHAP may be used as the substrate to characterize enzymes such as fructose bisphosphate aldolase and triose phosphate isomerase.

Actions biochimiques/physiologiques

Dihydroxyacetone phosphate (DHAP) is a metabolic intermediate involved in many pathways, including glycolysis, gluconeogenesis, glycerol metabolism, phosphatidic acid synthesis, fat metabolism, and the Calvin cycle.

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


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Consulter la Bibliothèque de documents

Inés Ardao et al.
Langmuir : the ACS journal of surfaces and colloids, 28(15), 6461-6467 (2012-03-21)
Gold nanoparticles (AuNPs) are attractive materials for the immobilization of enzymes due to several advantages such as high enzyme loading, absence of internal diffusion limitations, and Brownian motion in solution, compared to the conventional immobilization onto porous macroscopic supports. The
Alice Chan et al.
Angewandte Chemie (International ed. in English), 51(31), 7711-7714 (2012-06-21)
Stop for NadA! A [4Fe-4S] enzyme, NadA, catalyzes the formation of quinolinic acid in de novo nicotinamide adenine dinucleotide (NAD) biosynthesis. A structural analogue of an intermediate, 4,5-dithiohydroxyphthalic acid (DTHPA), has an in vivo NAD biosynthesis inhibiting activity in E. coli. The
Matthias Bujara et al.
Nature chemical biology, 7(5), 271-277 (2011-03-23)
Recruiting complex metabolic reaction networks for chemical synthesis has attracted considerable attention but frequently requires optimization of network composition and dynamics to reach sufficient productivity. As a design framework to predict optimal levels for all enzymes in the network is
Wei Lu et al.
Gene, 503(1), 65-74 (2012-05-09)
Fructose 1,6-biphosphate aldolase (FBA) is a key enzyme in plants, which is involved not only in glycolysis and gluconeogenesis in the cytoplasm, but also in the Calvin cycle in plastids. Research on FBAs in various organisms has been reported, but
Bjørn O Hald et al.
The FEBS journal, 279(23), 4410-4420 (2012-10-18)
Coherent glycolytic oscillations in Saccharomyces cerevisiae are a multicellular property induced by addition of glucose to a starved cell population of sufficient density. However, initiation of oscillations requires an additional perturbation, usually addition of cyanide. The fate of cyanide during

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