31640

4,4′-Diaminodiphenylmethane

analytical standard

• Synonyme(s) : DAPM, 4,4′-Methylenedianiline, MDA
• Formule empirique (notation de Hill): C₁₃H₁₄N₂
• Numéro CAS: 101-77-9
• Poids moléculaire : 198.26
• Numéro Beilstein : 474706
• Numéro CE : 202-974-4
• Numéro MDL: MFCD00007914
• Code UNSPSC : 41116107
• ID de substance PubChem : 329753859
• Nomenclature NACRES : NA.24

Propriétés

• Qualité: analytical standard
• Niveau de qualité: 100
• Durée de conservation: limited shelf life, expiry date on the label
• Technique(s): HPLC: suitable; gas chromatography (GC): suitable
• Pf: 88-92 °C
• Application(s): cleaning products; cosmetics; food and beverages; personal care
• Format: neat
• Chaîne SMILES: Nc1ccc(Cc2ccc(N)cc2)cc1
• InChI: 1S/C13H14N2/c14-12-5-1-10(2-6-12)9-11-3-7-13(15)8-4-11/h1-8H,9,14-15H2
• Clé InChI: YBRVSVVVWCFQMG-UHFFFAOYSA-N

Description

Description générale

4,4′-Diaminodiphenylmethane (MDA) is an aromatic diamine, which finds industrial applications as a precursor in the manufacturing of polyurethane products, isocyanates, polyisocyanates, etc. It is also used as a hardener in the production of epoxy resins and elastomers.

4,4′-Diaminodiphenylmethane is a curing agent for epoxy resins. It is prepared from formaldehyde aniline when heated with aniline hydrochloride and aniline.

Application

4,4′-Diaminodiphenylmethane is used as an analytical reference standard for the quantification of the analyte in the following:

• Urine samples using gas-chromatography coupled to mass spectrometry (GC-MS).
• Hepatic microsomal incubation mixture from rabbits using high-performance liquid chromatography-plasma spray mass spectrometry (HPLC-PSP-MS), offline HPLC with fast atom bombardment mass spectrometry (FAB-MS) and fast atom bombardment tandem mass spectrometry (FAB-MS/MS).

It is reported to be used in the synthesis of amino modified multi-walled carbon nanotubes/polydimethylsiloxane, which serves as a coating for the stir bar sorptive extraction (SBSE) of phenols in environmental samples, followed by analysis using high performance liquid chromatography with ultraviolet detection (HPLC-UV).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Informations sur la sécurité

• Pictogrammes: GHS06,GHS08,GHS09
• Mention d'avertissement: Danger
• Mentions de danger: H301,H317,H341,H350,H370,H373,H410
• Conseils de prudence: P202 - P260 - P273 - P280 - P301 + P310 - P302 + P352
• Classification des risques: Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 1B - Muta. 2 - Skin Sens. 1 - STOT RE 2 - STOT SE 1
• Organes cibles: Liver, Liver,eye - retina
• Code de la classe de stockage: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): 429.8 °F - closed cup
• Point d'éclair (°C): 221 °C - closed cup
• Équipement de protection individuelle: dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges