Accéder au contenu
Merck
Toutes les photos(1)

Key Documents

735817

Sigma-Aldrich

Polypyrrole-block-poly(caprolactone)

0.3-0.7 wt. % (dispersion in nitromethane), contains p-toluenesulfonate as dopant

Synonyme(s) :

Biotron PP-NM, PCL-block-PPy

Se connecterpour consulter vos tarifs contractuels et ceux de votre entreprise/organisme


About This Item

Code UNSPSC :
12352103
Nomenclature NACRES :
NA.23

Forme

liquid (dispersion)

Niveau de qualité

Contient

p-toluenesulfonate as dopant

Composition

Biotron PP polymer, 0.3-0.7 wt. %
ethanol, 4-8 wt. %
nitromethane, 90-95 wt. %

Concentration

0.3-0.7 wt. % (dispersion in nitromethane)

Conductivité

10-40 S/cm (bulk)

Description générale

Sheet resistance, spin cast thin films: 10,000-50,000 Ohms/sq

Average transmittance: 70-90%

Biodegradble conducting polymer for bomedical applications. PCL diol blocks have average molecular weight 2000 and PPy block have an average molecular weight of 4000 with a 25% doping level. Good biocompatibility with expected weight loss of 40% at 200 days in pH=7 buffer.

Application

Thin films can be prepared by spin casting the nitromethane dispersion at 1000 rpm. To spin coat a thin film at 1000 RPM, 30 seconds to 1 minute is usually enough time to spread this dispersion. Thicker and more conducting films can be prepared by air spraying the dispersion on a substrate. Any substrate that is compatible can be used. Sprayed films can be dried at 30-40 °C, then pressed between two polished dye plates at 1000-10,000 psi to increase film density, strength and scratch resistance. The drying time of the air sprayed film depends on the thickness of the prepared film. Try weighing the sample periodically during drying.

Caractéristiques et avantages

The block copolymer structure renders the conducting polymer polypyrrole dispersible in organic solvents and biodegradable.

Attention

Store this product at room temperature (do not refrigerate or freeze). Severe settling and separation will normally occur. Agitate, sonicate, and filter prior to use. A plug of glass wool in a pipette can be used for easy filtration. The shelf life of this product will vary depending on how it is stored and handled. Product should be discarded if heavy aggregation occurs, or if sonication / filtering are inadequate to produce a good casting solution. When spray coating is used, the user should take every precaution necessarily to prevent exposure to solvent vapors from this product

Autres remarques

Will settle over time. Must be sonicated before use

Informations légales

Pictogrammes

FlameHealth hazardExclamation mark

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Repr. 2

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

66.9 °F

Point d'éclair (°C)

19.4 °C


Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number

Vous ne trouvez pas la bonne version ?

Si vous avez besoin d'une version particulière, vous pouvez rechercher un certificat spécifique par le numéro de lot.

Déjà en possession de ce produit ?

Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Materials for Bioelectronic and
Biomedical Applications
Zhang Y, et al.
Material Matters, 8(1) null
Chemical Synthesis and Morphology of b?Naphthalene Sulfonic Acid-Doped Polypyrrole Micro/Nanotube.
Akinyeye R, et al.
Fullerenes, Nanotubes, and Carbon Nanostructures, 14 (2006)
Synergic effect in electrical conductivity using a combination of two fillers in PVDF hybrids composites.
da Silva AB, et al.
European Polymer Journal, 49(10), 3318-3327 (2013)
Polypropylene composites for polymer electrolyte membrane fuel cell bipolar plates.
Yeetsorn R, et al.
Macromolecular Symposia, 264(1) (2008)
Soluble conducting polypyrrole doped with DBSA?CSA mixed acid
Shen Y and Wan M
Journal of Applied Polymer Science, 68(8), 1277-1284 (1998)

Articles

The application of conducting polymers at the interface with biology is an exciting new trend in organic electronics research.

Organic materials in optoelectronic devices like LEDs and solar cells are of significant academic and commercial interest.

Organic materials in optoelectronic devices like LEDs and solar cells are of significant academic and commercial interest.

Organic materials in optoelectronic devices like LEDs and solar cells are of significant academic and commercial interest.

Afficher tout

Notre équipe de scientifiques dispose d'une expérience dans tous les secteurs de la recherche, notamment en sciences de la vie, science des matériaux, synthèse chimique, chromatographie, analyse et dans de nombreux autres domaines..

Contacter notre Service technique