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471836

Sigma-Aldrich

1-Octanethiol

≥98.5%

Sinónimos:

n-Octyl mercaptan, Mercaptan C8, Octyl mercaptan

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25 ML
43,90 €
250 ML
58,00 €
2 L
378,00 €
5 L
589,00 €

43,90 €

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25 ML
43,90 €
250 ML
58,00 €
2 L
378,00 €
5 L
589,00 €

About This Item

Fórmula lineal:
CH3(CH2)7SH
Número de CAS:
111-88-6
Peso molecular:
146.29
Beilstein:
1733101
Número CE:
203-918-1
Número MDL:
MFCD00004912
Código UNSPSC:
12352103
ID de la sustancia en PubChem:
24870763
NACRES:
NA.23

43,90 €

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Nivel de calidad

200

Ensayo

≥98.5%

índice de refracción

n20/D 1.452 (lit.)

bp

197-200 °C (lit.)

densidad

0.843 g/mL at 25 °C (lit.)

cadena SMILES

CCCCCCCCS

InChI

1S/C8H18S/c1-2-3-4-5-6-7-8-9/h9H,2-8H2,1H3

Clave InChI

KZCOBXFFBQJQHH-UHFFFAOYSA-N

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Descripción general

1-Octanethiol (OT) is C8 alkanethiol that forms self-assembled monolayer (SAM) on a variety of nanoparticles. It has a low flash point and low vapor pressure. [1][2]

Aplicación

OT can be used as a sulfur precursor for the preparation of shell for CdSe/CdS quantum dots.[3] It forms ligands that help in enhancing the power efficiency of hetero-junction nanorod sensitized solar cells as it enhances the electron extraction from the nanorod and TiO2 interface.[4] OT based stabilized coating on copper nanoparticles (CuNPs) may be used in the dispersion of these colloidal particles in different sample solutions.[1] It can be used to improve charge injection by creating a monolayer on gold source-drain electrode surfaces for bottom-contact thin-film transistors (TFTs).[5]

Información legal

Product of Arkema Inc.

Pictogramas

Exclamation markEnvironment
GHS07,GHS09

Palabra de señalización

Warning

Frases de peligro

H317,H335,H410

Clasificaciones de peligro

Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1 - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

10 - Combustible liquids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

154.4 °F - closed cup

Punto de inflamabilidad (°C)

68 °C - closed cup

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
SHBS0054
SHBP0383
SHBN1877
SHBM5322
SHBL7132

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Adsorption structures of 1-octanethiol on Cu (111) studied by scanning tunneling microscopy.
Driver SM and Woodruff DP
Langmuir, 16(16), 6693-6700 (2000)
David Doblas et al.
Nano letters, 19(8), 5246-5252 (2019-06-30)
We studied the concentration-dependent agglomeration of apolar nanoparticles in different solvents. Octanethiol-stabilized gold nanoparticles (AuNPs) in evaporating liquid droplets were observed in situ using small-angle X-ray scattering. Concurrent analysis of liquid volume and particle agglomeration provided time-dependent absolute concentrations of
Takane Imaoka et al.
Nature communications, 8(1), 688-688 (2017-09-28)
Subnanometer noble metal clusters have enormous potential, mainly for catalytic applications. Because a difference of only one atom may cause significant changes in their reactivity, a preparation method with atomic-level precision is essential. Although such a precision with enough scalability
Jean-François Lemineur et al.
Langmuir : the ACS journal of surfaces and colloids, 32(46), 12056-12066 (2016-10-28)
A method is described for the in situ growth of substrate-supported organized gold nanoparticles. Upon exposure to an aqueous solution of a gold salt and a mild reducing agent, the particle size can be significantly increased without any loss of
Influence of alkanethiols on fluorescence blinking of InP@ ZnS colloidal quantum dots.
Gak VY, et al.
High Energy Chemistry, 51(2), 118-121 (2017)
Ver todos los artículos relacionados

Artículos

Photopatterning Self-Assembled Monolayers

Self-assembled monolayers (SAMs) have diverse applications; article compares benefits of alkylthiolates on gold SAM systems.

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 respuesta

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 respuesta

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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