394378

4-Bromo-2,6-di-tert-butylphenol

98%

• Sinónimos: 2,6-Di-tert-butyl-4-bromophenol, 4-Bromo-2,6-bis(1,1-dimethylethyl)phenol, 4-Hydroxy-3,5-di(tert-butyl)bromobenzene
• Fórmula lineal: BrC₆H₂[C(CH₃)₃]₂OH
• Número de CAS: 1139-52-2
• Peso molecular: 285.22
• Beilstein: 2051052
• Número CE: 214-521-8
• Número MDL: MFCD00051598
• Código UNSPSC: 12352100
• ID de la sustancia en PubChem: 24864590
• NACRES: NA.22

Propiedades

• Ensayo: 98%
• Formulario: solid
• mp: 78-83 °C (dec.) (lit.)
• grupo funcional: bromo
• cadena SMILES: CC(C)(C)c1cc(Br)cc(c1O)C(C)(C)C
• InChI: 1S/C14H21BrO/c1-13(2,3)10-7-9(15)8-11(12(10)16)14(4,5)6/h7-8,16H,1-6H3
• Clave InChI: SSQQUEKFNSJLKX-UHFFFAOYSA-N

Descripción

Descripción general

4-Bromo-2,6-di-tert-butylphenol is a 4-substituted-2,6-di-tert-butylphenol. It is synthesized by the bromination of 2,6-di-tert-butylphenol. The structure was confirmed by ¹H NMR.[1] Its photolysis reaction in benzene solution has been investigated.[2] The photochemical reaction of 4-bromo-2,6-di-tert-butylphenol single crystals doped with 2,6-di-tert-butyl-p-quinone has been studied by EPR spectroscopy.[3]

Aplicación

4-Bromo-2,6-di-tert-butylphenol may be used in the following studies:

• As a terminating comonomer phenol in the phase transfer catalyzed (PTC) polymerization of 4-bromo-2,6-dimethylphenol.[1]
• Synthesis of 1,1-[1,10-decanediylbis(oxy)]bis[(2,6-ditertbutyl-4-bromo)benzene], a monomer, which forms poly(p-phenylenevinylene) derivatives by reaction with 1,10-dibromodecane.[4]
• As a reactant in the synthesis of 2,6-di-tert-butyl-phenolnorbornene (N_ArOH), a norbornene comonomer bearing an antioxidant hindered phenol.[5]
• As a catalyst with methyl aluminium to form methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide) (MABR) which may be utilized for the transformation of various epoxides to carbonyl compounds.[6][7]

Información de seguridad

• Pictogramas: GHS07
• Palabra de señalización: Warning
• Frases de peligro: H315,H319,H335
• Consejos de prudencia: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Clasificaciones de peligro: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Órganos de actuación: Respiratory system
• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable
• Equipo de protección personal: dust mask type N95 (US), Eyeshields, Gloves