381322
4,4′-Difluorobenzil
98%
Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización
About This Item
Fórmula lineal:
FC6H4COCOC6H4F
Número de CAS:
Peso molecular:
246.21
Número MDL:
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
Productos recomendados
Análisis
98%
mp
120-122 °C (lit.)
cadena SMILES
Fc1ccc(cc1)C(=O)C(=O)c2ccc(F)cc2
InChI
1S/C14H8F2O2/c15-11-5-1-9(2-6-11)13(17)14(18)10-3-7-12(16)8-4-10/h1-8H
Clave InChI
BRKULQOUSCHDGS-UHFFFAOYSA-N
Información sobre el gen
human ... ACHE(43) , BCHE(590) , CES1(1066)
Descripción general
4,4′-Difluorobenzil is a benzil derivative. Its reaction with benzylurea and phenethylurea has been investigated. It is reported to undergo condensation with Fe2(SH)2(CO)6 to afford the adduct Fe2[S2C2(OH)2(C6H4-4-F)2](CO)6.
Aplicación
4,4′-Difluorobenzil is suitable for use in the preparation of 2,3-bis(4-fluorophenyl)thieno[3,4-b]pyrazine. It may be used in the synthesis of following:
- poly(ether-α-diketone)s, via nucleophilic substitution reaction with bisphenol A
- 4,4′-difluoro-2,3-diphenylpyrazine (DPPF) and 4,4′-difluoro-5-methyl 2,3-diphenylpyrazine (MDPPF), via direct condensation with ethylenediamine and 1,2-diaminopropane, respectively
- 2,3-bis(4-fluorophenyl)quinoxaline, via direct condensation with 1,2-phenylenediamine
Palabra de señalización
Warning
Frases de peligro
Consejos de prudencia
Clasificaciones de peligro
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Órganos de actuación
Respiratory system
Código de clase de almacenamiento
11 - Combustible Solids
Clase de riesgo para el agua (WGK)
WGK 3
Punto de inflamabilidad (°F)
Not applicable
Punto de inflamabilidad (°C)
Not applicable
Equipo de protección personal
dust mask type N95 (US), Eyeshields, Gloves
Elija entre una de las versiones más recientes:
¿Ya tiene este producto?
Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.
Jane L Stanley et al.
Organometallics, 26(8), 1907-1911 (2008-07-02)
Reaction of Fe(2)(SH)(2)(CO)(6) and HCHO, which gives Fe(2)[(SCH(2))(2)NH](CO)(6) in the presence of NH(3), affords the possible intermediate Fe(2)(SCH(2)OH)(2)(CO)(6), which has been characterized crystallographically as its axial-equatorial isomer. Fe(2)(SCH(2)OH)(2)(CO)(6) was shown to react with ammonia and amines to give Fe(2)[(SCH(2))(2)NR](CO)(6) (R
Giulio G Muccioli et al.
Organic letters, 5(20), 3599-3602 (2003-09-26)
[reaction: see text] A new access to benzhydryl-phenylureas is described. These new interesting urea derivatives were obtained by reaction of substituted benzils with substituted phenylureas under microwave irradiation. Phenylthiourea, when reacted with benzil, gave 3-phenyl-thiohydantoin. Moreover, benzylurea, as phenethylurea, gave
Synthesis and Characterization of N-(2-Ethylhexyl) carbazole-2, 3-Bis (4-fluorophenyl)) thieno [3, 4-b] pyrazine Copolymer.
Li JC, et al.
Bull. Korean Chem. Soc., 31(7), 2073-2076 (2010)
Yellow organic light-emitting diodes based on phosphorescent iridium (III) pyrazine complexes: Fine tuning of emission color.
Ge G, et al.
Inorgorganica Chimica Acta, 362(7), 2231-2226 (2009)
Fu-Ming Hwang et al.
Inorganic chemistry, 44(5), 1344-1353 (2005-03-01)
Rational design and syntheses of four iridium complexes (1-4) bearing two substituted quinoxalines and an additional 5-(2-pyridyl) pyrazolate or triazolate as the third coordinating ligand are reported. Single-crystal X-ray diffraction studies of 1 reveal a distorted octahedral geometry, in which
Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.
Póngase en contacto con el Servicio técnico