177261

DPPF

97%

• Sinónimos: 1,1′-Ferrocenediyl-bis(diphenylphosphine), dppf
• Fórmula empírica (notación de Hill): C₃₄H₂₈FeP₂
• Número de CAS: 12150-46-8
• Peso molecular: 554.38
• Número MDL: MFCD00001422
• Código UNSPSC: 12350000
• ID de la sustancia en PubChem: 24850625
• NACRES: NA.22

Propiedades

• Análisis: 97%
• formulario: powder
• idoneidad de la reacción: reaction type: Cross Couplings; reagent type: ligand; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reagent type: ligand; reaction type: Carbonylations; reagent type: ligand; reaction type: Ene Reaction; reagent type: ligand; reaction type: Heck Reaction; reagent type: ligand; reaction type: Negishi Coupling; reagent type: ligand; reaction type: Sonogashira Coupling; reagent type: ligand; reaction type: Stille Coupling; reagent type: ligand; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Tsuji-Trost Reaction
• características de los productos alternativos más sostenibles: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 181-182 °C (dec.) (lit.)
• grupo funcional: phosphine
• categoría alternativa más sostenible: Aligned,
• cadena SMILES: [Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
• InChI: 1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;
• Clave InChI: HPXNTHKXCYMIJL-UHFFFAOYSA-N

Descripción

Descripción general

Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Aplicación

Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

Ligand used in a Pd(II)-catalyzed cross-coupling synthesis of oxazepine ring systems.

Información de seguridad

• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable
• Equipo de protección personal: Eyeshields, Gloves, type N95 (US)