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115150

Sigma-Aldrich

Thiophosgene

Sinónimos:

Thiocarbonyl chloride

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5 G
31,80 €
25 G
89,10 €
100 G
115,00 €

31,80 €

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5 G
31,80 €
25 G
89,10 €
100 G
115,00 €

About This Item

Fórmula lineal:
CSCl2
Número de CAS:
463-71-8
Peso molecular:
114.98
Beilstein:
1633495
Número CE:
207-341-6
Número MDL:
MFCD00004918
Código UNSPSC:
12352000
eCl@ss:
38020402
ID de la sustancia en PubChem:
24847201
NACRES:
NA.22

31,80 €

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densidad de vapor

4 (vs air)

Nivel de calidad

200

idoneidad de la reacción

reaction type: Carbonylations

índice de refracción

n20/D 1.548 (lit.)

bp

70-75 °C (lit.)

densidad

1.50 g/mL at 20 °C (lit.)

grupo funcional

chloro

temp. de almacenamiento

2-8°C

cadena SMILES

ClC(Cl)=S

InChI

1S/CCl2S/c2-1(3)4

Clave InChI

ZWZVWGITAAIFPS-UHFFFAOYSA-N

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Aplicación

Reagent used to prepare a bulky thiourea ligand for palladium-catalyzed aerobic oxidation of alcohols to aldehydes and ketones.[1]

Pictogramas

Skull and crossbonesCorrosion
GHS06,GHS05

Palabra de señalización

Danger

Frases de peligro

H302,H315,H318,H331,H335

Clasificaciones de peligro

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Clase de riesgo para el agua (WGK)

WGK 1

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
STBJ7925
STBH8658
STBH9037
STBH9036
STBH8659

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Visite la Librería de documentos

T A Lewis et al.
Journal of bacteriology, 177(8), 2204-2208 (1995-04-01)
Pseudomonas sp. strain KC transforms carbon tetrachloride into carbon dioxide and nonvolatile products, without chloroform as an intermediate. To define the pathway for hydrolysis, nonvolatile products were analyzed. Condensation products containing the carbon atom of carbon tetrachloride as carbonyl and
Christof Jung et al.
The journal of physical chemistry. A, 110(16), 5317-5325 (2006-04-21)
The dispersed fluorescence spectrum of the ground electronic state of thiophosgene, SCCl2, is analyzed in a very complex region of vibrational excitation, 7000-9000 cm(-1). The final result is that most of the inferred excited vibrational levels are assigned in terms
Cheng Li et al.
Colloids and surfaces. B, Biointerfaces, 171, 159-166 (2018-07-22)
Dual mode imaging technology is widely developed to achieve the early-stage precision cancer diagnosis. Here we designed a dual-modal magnetic resonance/near infrared fluorescence optical imaging contrast agent (GdF-SS-NIR783) with the fluorescence activatable and safer gadofullerene. The nanoprobes were fabricated by
W Kedzierski et al.
The Journal of chemical physics, 120(19), 9087-9089 (2004-07-23)
A special xenon matrix detector has been used to study the production of S(1S) following controlled electron impact on thiophosgene (Cl2CS) targets over an electron energy range from threshold to 400 eV. Time-of-flight spectroscopy has been used to measure S(1S)
Youlia Hagooly et al.
The Journal of organic chemistry, 73(17), 6780-6783 (2008-08-13)
A general preparation for aromatic and aliphatic, cyclic as well as linear, symmetric and asymmetric difluoromethylenedioxy derivatives is described. The alcohols were reacted with thiophosgene to give thiocarbonates, which in turn were reacted with BrF3. The fluorination step is complete
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Preguntas

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 respuesta

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 respuesta

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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