Both products are formulated to contain approximately 0.35% Iodine and 0.70% Potassium Iodide. While the concentration of L6146 is a bit higher at 0.37% Iodine and 0.74% Potassium Iodide, there is no functional difference between these two products. The formulations are typical for use in microscopy. The L6146 was originally a Sigma brand product while the 62650 was originally a Fluka brand product. Both now fall under the Sigma-Aldrich brand of products. The L6146 is tested for appearance and density, however, the 62650 has additional titration testing done to verify the concentration of each component. See the links below for a sample Certificate of Analysis for each product:
L6146
https://www.sigmaaldrich.com/certificates/Graphics/COfAInfo/fluka/pdf/PDF735903.pdf
62650
https://www.sigmaaldrich.com/certificates/sapfs/PROD/sap/certificate_pdfs/COFA/Q14/32922-BULKBCBZ9559.pdf