Accéder au contenu
Merck

Dry vs soaked wood: modulating the volatile extractible fraction of oak wood by heat treatments.

Food chemistry (2012-12-26)
Charlie J Duval, Nicolas Sok, Jérémy Laroche, Karine Gourrat, Andréi Prida, Sonia Lequin, David Chassagne, Régis D Gougeon
RÉSUMÉ

The aim of this study was to analyze the impact of the water content of wood on the concentrations of volatile compounds which can be extracted after heat treatments. Head Space-Solid Phase Micro Extraction Gas Chromatography coupled to Mass Spectrometry (HS-SPME GC-MS) has been used to compare the concentrations of six aroma compounds (vanillin, furfural, eugenol, guaïacol and cis- and trans-whisky lactones) in hydroalcoholic extracts of heated oak wood samples either previously soaked in hot water or not. Except for eugenol, concentrations of extracted aromas appeared to be lower in soaked woods than in dry woods for temperatures up to 200 °C. If a delaying effect of water could explain such overall lower extracted concentrations from soaked woods, a PCA analysis revealed that for the longer duration (25 min of heat treatment), the adsorbed water could promote a higher impact of furfural, eugenol and both whisky lactones on the composition of hydroalcoholic extracts, suggesting that alternative mechanisms of thermal modifications of the wood macromolecular network could exist at high temperatures in presence of adsorbed water.

MATÉRIAUX
Référence du produit
Marque
Description du produit

Supelco
Ensemble de fibres de SPME, divinylbenzène/carboxène/polydiméthylsiloxane (DVB/CAR/PDMS), 50/30µm DVB/CAR/PDMS, StableFlex (2cm), needle size 24 ga, Autosampler, pk of 3, notched gray hub
Supelco
Ensemble de fibres de SPME, divinylbenzène/carboxène/polydiméthylsiloxane (DVB/CAR/PDMS), 50/30µm DVB/CAR/PDMS, StableFlex (1cm), needle size 24 ga, Manual Holder, pk of 3, plain gray hub
Supelco
Ensemble de fibres de SPME, divinylbenzène/carboxène/polydiméthylsiloxane (DVB/CAR/PDMS), 50/30µm DVB/CAR/PDMS, StableFlex (1 cm), needle size 23 ga, Autosampler, pk of 3, plain gray hub
Sigma-Aldrich
Gaïacol, oxidation indicator
Supelco
Ensemble de fibres de SPME, divinylbenzène/carboxène/polydiméthylsiloxane (DVB/CAR/PDMS), 50/30µm DVB/CAR/PDMS, StableFlex (1 cm), needle size 24 ga, Autosampler, pk of 3, plain gray hub
Supelco
Ensemble de fibres de SPME, divinylbenzène/carboxène/polydiméthylsiloxane (DVB/CAR/PDMS), 50/30µm DVB/CAR/PDMS, StableFlex (2cm), needle size 23 ga, Autosampler, pk of 3, notched gray hub
Supelco
Fibres SPME polydiméthylsiloxane (PDMS), df 100 μm(PDMS, for use with autosampler, needle size 23 ga
Sigma-Aldrich
Gaïacol, natural, ≥99%, FG
Supelco
Fibres SPME polydiméthylsiloxane (PDMS), df 100 μm(PDMS, needle size 24 ga, for use with manual holder
Supelco
Fibres SPME polydiméthylsiloxane (PDMS), df 100 μm(PDMS, for use with autosampler, needle size 24 ga
Supelco
Unité de fibres SPME, carboxène/polydiméthylsiloxane (CAR/PDMS), df 75 μm(CAR/PDMS, for use with manual holder, needle size 24 ga
Sigma-Aldrich
Furfural, ≥98%, FCC, FG
Supelco
Unité de fibres SPME, Polydiméthylsiloxane/divinylbenzène (PDMS/DVB), df 65 μm(PDMS/DVB, needle size 24 ga, StableFlex, for use with autosampler
Supelco
Unité de fibres SPME, carboxène/polydiméthylsiloxane (CAR/PDMS), df 85 μm(CAR/PDMS, needle size 23 ga, StableFlex, for use with autosampler
Supelco
Unité de fibres SPME, carboxène/polydiméthylsiloxane (CAR/PDMS), df 85 μm(CAR/PDMS, needle size 24 ga, StableFlex, for use with autosampler
Supelco
Fibres SPME polyacrylate (PA), df 85 μm(PA, for use with autosampler, needle size 23 ga
Supelco
Unité de fibres SPME, Polydiméthylsiloxane/divinylbenzène (PDMS/DVB), df 65 μm(PDMS/DVB, needle size 24 ga, for use with manual holder
Supelco
Unité de fibres SPME, Polydiméthylsiloxane/divinylbenzène (PDMS/DVB), df 65 μm(PDMS/DVB, needle size 23 ga, PDMS/DVB StableFlex, for use with autosampler
Sigma-Aldrich
Furfural, natural, ≥98%, FCC, FG
Sigma-Aldrich
Furfural, 99%
Supelco
Unité de fibres SPME, carboxène/polydiméthylsiloxane (CAR/PDMS), df 75 μm(CAR/PDMS, needle size 24 ga, for use with autosampler
Supelco
Unité de fibres SPME, Polydiméthylsiloxane/divinylbenzène (PDMS/DVB), df 65 μm(PDMS/DVB, needle size 24 ga, for use with autosampler
Supelco
Unité de fibres SPME, carboxène/polydiméthylsiloxane (CAR/PDMS), df 85 μm(CAR/PDMS, needle size 24 ga, for use with manual holder, StableFlex fiber
Supelco
Unité de fibres SPME, Polydiméthylsiloxane/divinylbenzène (PDMS/DVB), df 65 μm(PDMS/DVB, needle size 24 ga, StableFlex, for use with manual holder
Supelco
Fibres SPME polyacrylate (PA), df 85 μm(PA, for use with autosampler, needle size 24 ga
Supelco
Fibres SPME polydiméthylsiloxane (PDMS), df 100 μm(PDMS, for use with manual holder, needle size 23 ga
Supelco
Unité de fibres SPME, carboxène/polydiméthylsiloxane (CAR/PDMS), df 75 μm(CAR/PDMS, needle size 23 ga, for use with autosampler
Supelco
Unité de fibres SPME, Polydiméthylsiloxane/divinylbenzène (PDMS/DVB), df 65 μm(PDMS/DVB, for use with autosampler, needle size 23 ga
Supelco
Kit d'assortiment de fibres SPME StableFlex, for use with manual holder
Supelco
SPME fiber assembly, Carbowax-Polyethylene Glycol (PEG) Coating, needle size 23 ga, df 60 μm(PEG, for use with autosampler