923508

(iPrMPhos)PdCl₂

1:1 complex with CH₂Cl₂, ≥95%

• Synonyme(s) : 1-Diadamantylphosphino-1′-diisopropylphosphinoferrocene palladium dichloride
• Formule empirique (notation de Hill): C₃₆H₅₂Cl₂FeP₂Pd
• Poids moléculaire : 779.92
• Code UNSPSC : 12352103
• Nomenclature NACRES : NA.22

Propriétés

• Niveau de qualité: 100
• Pureté: ≥95%
• Forme: powder
• Pertinence de la réaction: reagent type: catalyst; reaction type: Cross Couplings
• Pf: >300 °C
• Chaîne SMILES: Cl[Pd](Cl)([P](c1cccc1)(C23C[C@H]4C[C@H](C[C@H](C4)C3)C2)C56C[C@H]7C[C@H](C[C@H](C7)C6)C5)[P](c8cccc8)(C(C)C)C(C)C.[Fe]

Description

Application

(iPrMPhos)PdCl₂ is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (iPrMPhos)PdCl₂ can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

Autres remarques

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable