923451

(PhMPhos)PdCl₂

complex with CH₂Cl₂

• Synonyme(s) : 1-Diadamantylphosphino-1′-diphenylphosphinoferrocene palladium dichloride
• Formule empirique (notation de Hill): C₄₂H₄₈Cl₂FeP₂Pd
• Numéro CAS: 2768152-18-5
• Poids moléculaire : 847.95
• Code UNSPSC : 12352101
• Nomenclature NACRES : NA.21

Propriétés

• Niveau de qualité: 100
• Forme: powder
• Pertinence de la réaction: reagent type: catalyst; reaction type: Cross Couplings

Description

Application

(PhMPhos)PdCl₂ is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (PhMPhos)PdCl₂ can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

Autres remarques

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

Informations sur la sécurité

• Pictogrammes: GHS08,GHS07
• Mention d'avertissement: Warning
• Mentions de danger: H315,H319,H351
• Conseils de prudence: P202 - P264 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Classification des risques: Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2
• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable