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288055

Sigma-Aldrich

Cyclopentadienylmanganese(I) tricarbonyl

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About This Item

Formule linéaire :
C5H5Mn(CO)3
Numéro CAS:
12079-65-1
Poids moléculaire :
204.06
Numéro CE :
235-142-4
Numéro MDL:
MFCD00001440
Code UNSPSC :
12352103
ID de substance PubChem :
24857312
Nomenclature NACRES :
NA.23

Niveau de qualité

100

Forme

powder or crystals

Composition

Mn, 26.0-27.9% EDTA titration

Pertinence de la réaction

core: manganese
reagent type: catalyst

Pf

72-76 °C (lit.)

Chaîne SMILES 

[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1

InChI

1S/C5H5.3CO.Mn/c1-2-4-5-3-1;3*1-2;/h1-5H;;;;

Clé InChI

CZPHEHHRMHXAIK-UHFFFAOYSA-N

Catégories apparentées

Pictogrammes

Skull and crossbones
GHS06

Mention d'avertissement

Danger

Mentions de danger

H300

Conseils de prudence

P264 - P301 + P310

Classification des risques

Acute Tox. 2 Oral

Code de la classe de stockage

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Cobalt carbonyl moistened with hexane (hexane 1-10%), ≥90% (Co)

Sigma-Aldrich

60811

Cobalt carbonyl

Benzene-chromium(0) tricarbonyl 98%

Sigma-Aldrich

119318

Benzene-chromium(0) tricarbonyl

K T Blanchard et al.
Toxicology letters, 70(2), 253-259 (1994-02-01)
The effect of m-xylene on the rat nasal cytochrome P450 (P450) mixed function oxidase system was analyzed in vitro utilizing microsomes isolated 2, 12, and 24 h following intraperitoneal administration of this solvent in vivo. For comparative purposes, pulmonary and
R J Clay et al.
Toxicology and applied pharmacology, 98(3), 434-443 (1989-05-01)
The acute pneumotoxic effects of cyclopentadienyl manganese tricarbonyl (CMT) and methylcyclopentadienyl manganese tricarbonyl (MMT) were compared to delineate the role of the methyl side chain in the toxicity of these organomanganese compounds and to further our understanding of the mechanisms
I Rémy et al.
Journal of pharmaceutical and biomedical analysis, 9(10-12), 965-967 (1991-01-01)
Biotin labelled with a cymantrene moiety (cyclopentadienyl manganese tricarbonyl complex) is described for the first time. Because this metallo-biotin retains full recognition for the specific glycoprotein avidin (or streptavidin), the labelled streptavidin-biotin system is proposed for use in a solid-phase
Magdaléna Hromadová et al.
Langmuir : the ACS journal of surfaces and colloids, 22(1), 506-511 (2005-12-28)
A first example of the solid-phase immunoassay of a high-weight antigen bovine serum albumin (BSA) using an (eta(5)-cyclopentadienyl)tricarbonylmanganese (cymantrene) redox probe is presented. The electrochemical detection is based on the impedance measurements of a one-electron reversible reduction of the organometallic
Katrin Splith et al.
Dalton transactions (Cambridge, England : 2003), 39(10), 2536-2545 (2010-02-25)
By combining organometallic groups and peptides, a large number of conjugates with interesting new biological properties can be prepared. Especially, attachment to cell-penetrating peptides (CPP) that act as efficient cell delivery vehicles has come to the fore. However, the presence
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