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708801

Sigma-Aldrich

Iron(III) trifluoromethanesulfonate

greener alternative

90%

Synonym(s):

Fe(CF3SO3)3, Ferric triflate, Ferric trifluoromethanesulfonate, Fe(CF3SO3)3, Fe(OTf)3, Iron 1,1,1-trifluoromethanesulfonic acid, Iron(III) triflate

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About This Item

Empirical Formula (Hill Notation):
C3F9FeO9S3
CAS Number:
63295-48-7
Molecular Weight:
503.05
MDL number:
MFCD15144785
UNSPSC Code:
12161600
PubChem Substance ID:
329762826
NACRES:
NA.22

Quality Level

100

Assay

90%

form

powder

reaction suitability

core: iron
reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

183 °C

greener alternative category

, Aligned

SMILES string

[Fe+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/3CHF3O3S.Fe/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3

InChI key

OSHOQERNFGVVRH-UHFFFAOYSA-K

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

>230.0 °F

Flash Point(C)

> 110 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000259018
SHBP6216
0000259018
SHBL8005
SHBJ1822

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Hai-Jie Song et al.
ChemSusChem, 8(24), 4250-4255 (2015-11-28)
Using a metal triflate and Pd/C as catalysts, alkanes were prepared from bioderived furans in a one-pot hydrodeoxygenation (HDO) process. During the reaction, the metal triflate plays a crucial role in the ring-opening HDO of furan compounds. The entire reaction
Yang Li et al.
Macromolecular bioscience, 20(11), e2000146-e2000146 (2020-06-23)
The conducting polymer polyethylenedioxythiophene doped with polystyrene sulfonate (PEDOT:PSS) has received great attention in the field of wearable bioelectronics due to its tunable high electrical conductivity, air stability, ease of processability, biocompatibility, and recently discovered self-healing ability. It has been
Imtiyaz Ahmad Wani et al.
Organic & biomolecular chemistry, 16(16), 2910-2922 (2018-04-06)
Direct and expedient access to densely substituted tetrahydrocarbazoles and tetrahydrocycloheptadiindoles bearing multiple contiguous stereocentres has been achieved via a two-fold divergent diastereoselective (dr up to >99 : 1) transformation of 2-vinylindoles. The high-yielding conversions (yield up to 87%) that are amenable for
Raffaele Cucciniello et al.
ChemSusChem, 9(23), 3272-3275 (2016-11-24)
The present work deals with the production of monoalkyl glyceryl ethers (MAGEs) through a new reaction pathway based on the reaction of glycidol and alcohols catalyzed by Lewis acid-based catalysts. Glycidol is quantitatively converted with high selectivity (99 %) into MAGEs

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