324647
Allylboronic acid pinacol ester
97%
Synonym(s):
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 4,4,5,5-tetramethyl-2-(2-propen-1-yl)-1,3,2-dioxaborolane, 4,4,5,5-tetramethyl-2-(2-propenyl)-1,3,2-dioxaborolane, Allyl pinacol boronate, Pinacol allylboronate, Pinacolyl 2-propenylboronate
About This Item
Recommended Products
Quality Level
Assay
97%
refractive index
n20/D 1.4268 (lit.)
bp
50-53 °C/5 mmHg (lit.)
density
0.896 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
CC1(C)OB(CC=C)OC1(C)C
InChI
1S/C9H17BO2/c1-6-7-10-11-8(2,3)9(4,5)12-10/h6H,1,7H2,2-5H3
InChI key
YMHIEPNFCBNQQU-UHFFFAOYSA-N
Related Categories
General description
Application
- Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis[2]
- Intermolecular radical additions[3]
- Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids[4]
- Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes[5]
- Nucleic acid-templated energy transfer leading to a photorelease reaction[6]
- Stereoselective indium-catalyzed Hosomi-Sakurai reactions[7]
Reagent used in Preparation of
- Cyclic sulfone hydroxyethylamines as BACE1 inhibitors for reduction of Amyloid β-Peptides[8]
- Transmetalation of carbene Ru iodide with Ag carboxylates to give C-H-activated Ru carbene complexes as catalysts for Z-selective olefin metathesis[9]
- Allylboronation reagent for the preparation of allylic alcohols[10], and homoallylic amines.[11]
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 3
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
114.8 °F - closed cup
Flash Point(C)
46 °C - closed cup
Personal Protective Equipment
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