CRM05671
Fenoxaprop-P-ethyl
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Synonym(e):
(R)-2-{4-[(6-Chlorbenzoxazol-2-yl)-oxy]-phenoxy}-propionsäure-ethylester
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About This Item
Empirische Formel (Hill-System):
C18H16ClNO5
CAS-Nummer:
Molekulargewicht:
361.78
Beilstein:
8158010
MDL-Nummer:
UNSPSC-Code:
41116107
NACRES:
NA.24
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Qualität
certified reference material
TraceCERT®
Qualitätsniveau
Produktlinie
TraceCERT®
Haltbarkeit
limited shelf life, expiry date on the label
Hersteller/Markenname
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Lagertemp.
2-8°C
SMILES String
CCOC(=O)[C@@H](C)Oc1ccc(Oc2nc3ccc(Cl)cc3o2)cc1
InChI
1S/C18H16ClNO5/c1-3-22-17(21)11(2)23-13-5-7-14(8-6-13)24-18-20-15-9-4-12(19)10-16(15)25-18/h4-11H,3H2,1-2H3/t11-/m1/s1
InChIKey
PQKBPHSEKWERTG-LLVKDONJSA-N
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Allgemeine Beschreibung
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. The CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Fenoxaprop-P-ethyl (FPE) is a post-emergence herbicide that is used on many crops, such as rice, wheat, and barley, against annual and perennial grasses. It is an aryloxyphenoxypropionate that shows contact and systemic action. Fenoxaprop-P-ethyl works by inhibiting the activity of acetyl coenzyme A carboxylase and disrupting the synthesis of fatty acids. It is quickly converted to its metabolite fenoxaprop acid (FPA), another herbicidally active compound, in soil and plants. As per the commission regulation no 1107/2009, repealing the council directive 91/414/EEC unless otherwise stated the data available for fenoxaprop-P relates to its variant fenoxaprop-P-ethyl. It was approved for use in European Union on 1st January 2009 and the approval expires on 31st December 2022. According to Regulation (EC) no. 149/2008, a maximum residue limit (MRL) of 0.1 mg/kg applies for fenoxaprop-P in fresh/frozen fruits and tree nuts.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Fenoxaprop-P-ethyl (FPE) is a post-emergence herbicide that is used on many crops, such as rice, wheat, and barley, against annual and perennial grasses. It is an aryloxyphenoxypropionate that shows contact and systemic action. Fenoxaprop-P-ethyl works by inhibiting the activity of acetyl coenzyme A carboxylase and disrupting the synthesis of fatty acids. It is quickly converted to its metabolite fenoxaprop acid (FPA), another herbicidally active compound, in soil and plants. As per the commission regulation no 1107/2009, repealing the council directive 91/414/EEC unless otherwise stated the data available for fenoxaprop-P relates to its variant fenoxaprop-P-ethyl. It was approved for use in European Union on 1st January 2009 and the approval expires on 31st December 2022. According to Regulation (EC) no. 149/2008, a maximum residue limit (MRL) of 0.1 mg/kg applies for fenoxaprop-P in fresh/frozen fruits and tree nuts.
Anwendung
The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The CRM may also find the following uses:
The CRM may also find the following uses:
- Development and validation of gas chromatography (GC) and high-performance liquid chromatography (HPLC) method to detect FPE and its two primary metabolites in rice plants, rice straw, and rice grain
- Study of the degradation of FPE and its metabolite in soil and wheat crops by high-performance liquid chromatography (HPLC) coupled with UV detector
- Determination of FPE in barley and wheat grain samples using UV-Vis spectrophotometer
- Residue analysis of FPE and its metabolite fenoxaprop acid using HPLC in the study to evaluate the persistence of the herbicide and its metabolite in soil, wheat grain, and straw
- Development of a multi-residue enzyme-linked immunosorbent assay (ELISA) to detect two aryloxyphenoxypropionate herbicides in water, rice, soil, and soybean samples
- Direct determination of FPE from water and crop samples by voltametric method and also analysis of its reduction behavior on a hanging mercury drop electrode (HMDE)
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Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Rechtliche Hinweise
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1 - STOT RE 2
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 2
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
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Analysenzertifikate (COA)
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Detection of aryloxyphenoxypropionate herbicides by enzyme-linked immunosorbent assay
Ren K, et al.
Analytical Letters, 831- 840 (2012)
Detection of the herbicide fenoxaprop-P-ethyl, its agronomic safener isoxadifen ethyl and their metabolites residue in rice
Lucini L and Molinari G P
Quality Assurance and Safety of Crops & Foods, 3(2), 63- 68 (2011)
Reduction behavior of fenoxaprop-p-ethyl and its voltammetric determination
Es Zeki and Tasdemir ? H
Turkish Journal of Chemistry, 54- 63 null
Shashi B Singh et al.
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 48(5), 324-330 (2013-02-26)
The persistence of fenoxaprop ethyl {Ethyl (RS)-2-[4-(6-chloro-1,3-benzoxazol-2-yloxy) phenoxy] propionate} herbicide and its active metabolite fenoxaprop acid was investigated in soil and wheat crop. Fenoxaprop acid was prepared by alkaline hydrolysis of fenoxaprop ethyl. A HPLC method was developed in which
Spectrophotometric method for the determination of fenoxaprop-p-ethyl herbicide in wheat and barley grains using charge transfer complex
Shehzad F N, et al.
Sarhad journal of agriculture, 28(1), 63- 68 (2012)
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