443808

tert-Butylmethylether

ACS reagent, ≥99.0%

• Synonym(e): MTBE, Methyl-tert.-butylether
• Lineare Formel: (CH₃)₃COCH₃
• CAS-Nummer: 1634-04-4
• Molekulargewicht: 88.15
• Beilstein: 1730942
• EG-Nummer: 216-653-1
• MDL-Nummer: MFCD00008812
• UNSPSC-Code: 12352112
• PubChem Substanz-ID: 329756503
• NACRES: NA.07
• bp: 55-56 °C (lit.)

Eigenschaften

• Qualität: ACS reagent
• Qualitätsniveau: 200
• Dampfdichte: 3.1 (vs air)
• Dampfdruck: 4.05 psi
• Assay: ≥99.0%
• Form: liquid
• Selbstzündungstemp.: 705 °F
• Expl.-Gr.: 15.1 %
• dilution: (for analytical testing)
• Verunreinigungen: ≤0.05% water; <1 ppm H₂O₂
• Abdampfrückstand: ≤0.001%
• Farbe: APHA: ≤10
• Brechungsindex: n20/D 1.369 (lit.)
• bp: 55-56 °C (lit.)
• mp (Schmelzpunkt): -110 °C
• Dichte: 0.74 g/mL at 25 °C (lit.)
• Anwendung(en): microbiology
• SMILES String: COC(C)(C)C
• InChI: 1S/C5H12O/c1-5(2,3)6-4/h1-4H3
• InChIKey: BZLVMXJERCGZMT-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

tert-Butyl methyl ether (methyl tert-butyl ether, MTBE) is a gasoline additive. Its oxidative degradation by propane-oxidizing bacterial strains has been tested.[1] Kinetics of its heat-mediated biodegradation has been investigated under various reaction conditions. Its biodegradation followed a pseudo-first-order decay model and its pseudo-first-order rate constants were evaluated.[2] Its extraction from water has been proposed by employing an organic polymeric compound, Nafion.[3] MTBE can be synthesized by acid-catalyzed reaction between methanol and isobutene.[4] A study suggests that the addition of MTBE increases the number of active sites during polymerization of propene by stopped-flow method.[5] This solvent meets ACS (American Chemical Society) specifications and can be used for processes requiring strict quality conditions such as analytical testing.

Anwendung

tert-Butyl methyl ether (methyl tert-butyl ether, MTBE) may be used:

• As sole carbon and energy source in a mixed microbial consortium.[6]
• To extract lipids from biological fluids for shotgun profiling.[7]
• To synthesize fatty acid methyl esters (FAMEs) and glycerol tert-butyl ether by transesterification of canola oil in the absence of catalyst under supercritical condition.[8]

Sicherheitshinweise

• Piktogramme: GHS02,GHS07
• Signalwort: Danger
• H-Sätze: H225,H315
• P-Sätze: P210 - P233 - P240 - P241 - P242 - P303 + P361 + P353
• Gefahreneinstufungen: Flam. Liq. 2 - Skin Irrit. 2
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 1
• Flammpunkt (°F): -18.4 °F - closed cup
• Flammpunkt (°C): -28 °C - closed cup