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Merck

258105

Sigma-Aldrich

Schwefelsäure

Sulfuric acid
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ACS reagent, 95.0-98.0%

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About This Item

Lineare Formel:
H2SO4
CAS-Nummer:
Molekulargewicht:
98.08
Beilstein:
2037554
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352106
PubChem Substanz-ID:
NACRES:
NA.21
Qualität:
ACS reagent
Agentur:
suitable for EPA 1613
suitable for SM 4500 - NH3
suitable for SM 5210
pH-Wert:
1.2 (5 g/L)
Preise und Verfügbarkeit sind derzeit nicht verfügbar.

Qualität

ACS reagent

Qualitätsniveau

Agentur

suitable for EPA 1613
suitable for SM 4500 - NH3
suitable for SM 5210

Dampfdichte

<0.3 (25 °C, vs air)

Dampfdruck

1 mmHg ( 146 °C)

Beschreibung

Free from suspended or insoluble matter
Nominally 95-98% H2SO4

Assay

95.0-98.0%

Form

liquid

Glührückstand

≤5 ppm

Farbe

APHA: ≤10

pH-Wert

1.2 (5 g/L)

bp

~290 °C (lit.)

Dichte

1.840 g/mL at 25 °C (lit.)

Anionenspuren

MnO4- reducers: ≤2 ppm
chloride (Cl-): ≤0.2 ppm
nitrate (NO3-): ≤0.5 ppm

Kationenspuren

As: ≤0.01 ppm
Fe: ≤0.2 ppm
Hg: ≤5 ppb
NH4+: ≤2 ppm
heavy metals (as Pb): ≤1 ppm

SMILES String

OS(O)(=O)=O

InChI

1S/H2O4S/c1-5(2,3)4/h(H2,1,2,3,4)

InChIKey

QAOWNCQODCNURD-UHFFFAOYSA-N

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Anwendung

Schwefelsäure kann als Katalysator für Folgendes verwendet werden:
  • Bei der Hydrolyse von primären oder sekundären Nitroalkansalzen zu Aldehyden oder Ketonen.
  • Bei der selektiven Hydrolyse von Nitrilen zu Amiden.
  • Bei der Synthese von t-Alkylcarbinaminen mittels Ritter-Reaktion zwischen Nitrilen und Alkenen.
  • Zum Herstellen von 3,4-Dialkyl-2(5H)-furanonen durch Carbonylierung von α,β-ungesättigten Aldehyden.
  • Bei der Nitrierung von aromatischen Carbocyclen und heteroaromatischen Verbindungen.
  • Bei der Friedel-Craft-Ketonsynthese mit Anhydriden mittels α-Amidoalkylierungsreaktion.

H2SO4 kann auch in folgenden Reaktionen eingesetzt werden:
  • Michael-Additionsreaktionen
  • Elektrophile Substitutionsreaktionen
  • Veresterung von stark gehinderten aromatischen Säuren
  • Aldol-Kondensationsreaktion
  • Beckmann-Umlagerung
  • Hofmann-Löffler-Freytag-Reaktion
  • Isomerisation
  • Dehydrierung
  • Sulfonierung

Sonstige Hinweise

ACS-Spezifikation wie bei Produkt 320501
4L und 4X4L sind in Polyflaschen verpackt
SKU-Packungsgrößen mit dem Zusatz -PC sind in PVC-beschichteten Glasflaschen verpackt.

Piktogramme

Corrosion

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Lagerklassenschlüssel

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Tim Olding et al.
Physics in medicine and biology, 56(5), 1259-1279 (2011-02-03)
This work develops imaging protocols for improved dose readout of a Fricke-xylenol orange-gelatin (FXG) gel-filled 1 L polyethylene terephthalate (PETE) jar dosimeter using a commercial Vista(TM) cone-beam optical computed tomography (CT) scanner from Modus Medical Devices Inc. (London, ON, Canada).
Determination of mercury in natural waters and effluents by flameless atomic absorption spectrophotometry.
S H Omang
Analytica chimica acta, 53(2), 415-419 (1971-02-01)
Investigation of the kinetics and mechanism of the anodic oxidation of aniline in aqueous sulfuric acid solution at a platinum electrode.
Mohilner DM, et al.
Journal of the American Chemical Society, 84(19), 3618-3622 (1962)
Jing Li et al.
Journal of chromatography. A, 1404, 39-43 (2015-06-09)
The paper reports on a novel method for rapid determination of carbonyl in lignins by headspace gas chromatography (HS-GC). The method involves the quantitative carbonyl reduction for aldehydes in 2min at room temperature or for acetones in 30min at 80°C
Steven Babic et al.
Physics in medicine and biology, 53(6), 1637-1650 (2008-03-28)
Freshly prepared radiochromic ferrous xylenol-orange (FX) gels optically scanned with a light source exhibit a threshold dose response that is thermally and wavelength dependent. Correction for this threshold dose leads to accurate dose calibration and better reproducibility in multiple fraction

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Protokolle

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Verwandter Inhalt

This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.

Fragen

1-9 von 9 Fragen  
  1. Is the range of concentration listed have to do with volume or will an exact percentage be available on the bottle when received for the purposes of further dilution.

    1 Antwort
    1. The specification for this product (95.0 to 98.0 percent) is for the weight percent of the sulfuric acid; the remaining 2 to 5 percent by weight is water. The lot-specific weight percent is reported as the Purity by Sodium Hydroxide (NaOH) titration on the certificate of analysis for each lot. The result is not printed on the bottle. Practically speaking, whether the percentage is 95.0 percent or 98.0 percent or somewhere in between, the material would be handled the same way.

      Hilfreich?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 Antwort
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Hilfreich?

  3. How can I determine the shelf life / expiration / retest date of this product?

    1 Antwort
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Hilfreich?

  4. Difference between 258105-500ML, and 258105-500ML-PC, Mainly the PC part of the partnumber.

    1 Antwort
    1. Product 258105-500ML is packaged in a poly bottle, The package sizes listing the -PC suffix, including 258105-500ML-PC, are packaged in PVC-coated glass bottles.

      Hilfreich?

  5. What is Sulfuric acid, Product 258105, dissolved in?

    1 Antwort
    1. This material is not dissolved in anything.  Rather it is pure sulfuric acid, which is a liquid at room temperature.

      Hilfreich?

  6. What is the Department of Transportation shipping information for this product?

    1 Antwort
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Hilfreich?

  7. How was the concentration of Sulfuric acid, Product 258105, calculated?

    1 Antwort
    1. The molarity is calculated using the following equation:molarity=[(1000 X Density)/molecular weight] X (percent purity/100).

      Hilfreich?

  8. What is the concentration of Sulfuric acid, Product 258105, in moles per liter (M)?

    1 Antwort
    1. This material has a calculated, theoretical concentration of 18 M.

      Hilfreich?

  9. How is Sulfuric acid, Product 258105, to be stored?

    1 Antwort
    1. This material is a room temperature storage item.

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