B92001

4-tert-Butylcyclohexanol, Gemisch aus cis und trans

98%

• Lineare Formel: (CH₃)₃CC₆H₁₀OH
• CAS-Nummer: 98-52-2
• Molekulargewicht: 156.27
• Beilstein: 1902277
• EG-Nummer: 202-676-4
• MDL-Nummer: MFCD00001473
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24892127
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• Form: powder
• bp: 110-115 °C/15 mmHg (lit.)
• mp (Schmelzpunkt): 62-70 °C (lit.)
• SMILES String: CC(C)(C)C1CCC(O)CC1
• InChI: 1S/C10H20O/c1-10(2,3)8-4-6-9(11)7-5-8/h8-9,11H,4-7H2,1-3H3
• InChIKey: CCOQPGVQAWPUPE-UHFFFAOYSA-N

Beschreibung

Anwendung

4-tert-Butylcyclohexanol (mixture of cis and trans) can be used as a reactant to synthesize tris(4,4′-di-tert-butyl-2,2′-bipyridine)(trans-4-tert-butylcyclohexanolato)deca-μ-oxido-heptaoxidoheptavanadium oxide cluster complex by reacting with [V₈O₂₀(C₁₈H₂₄N₂)₄]. It can also be used as a reactant in competitive Oppenauer oxidation experiments in the presence of zeolite BEA as a stereoselective catalyst. Only cis-isomer is selectively converted to the corresponding ketone, whereas trans-isomer remains unchanged.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H319
• P-Sätze: P264 - P280 - P305 + P351 + P338 - P337 + P313
• Gefahreneinstufungen: Eye Irrit. 2
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 1
• Flammpunkt (°F): 221.0 °F - closed cup
• Flammpunkt (°C): 105 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)