939633

Indoline-2-thione

≥-95%

• Synonym(e): 2,3-Dihydro-1H-indole-2-thione
• Empirische Formel (Hill-System): C₈H₇NS
• CAS-Nummer: 496-30-0
• Molekulargewicht: 149.21
• MDL-Nummer: MFCD09971323
• UNSPSC-Code: 12352100

Eigenschaften

• Qualitätsniveau: 100
• Assay: ≥-95%
• Form: powder or crystals
• Eignung der Reaktion: reaction type: Photocatalysis
• Grünere Alternativprodukt-Eigenschaften: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Farbe: white to yellow
• Grünere Alternativprodukt-Kategorie: Aligned
• SMILES String: S=C1NC2=CC=CC=C2C1
• InChI: InChI=1S/C8H7NS/c10-8-5-6-3-1-2-4-7(6)9-8/h1-4H,5H2,(H,9,10)
• InChIKey: IGJWTYFTQNHSEK-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Anwendung

Indoline-2-thione is a indole thiolate has been used in:

• The MgI₂-catalyzed nucleophilic ring opening of donor-acceptor cyclopropanes[1]
• The synthesis of indole-fused dihydrothiopyrano scaffolds via [3+3] annulations of donor-acceptor cyclopropanes[2]
• The preparation of 2-carboxylated thieno [2,3- b] indoles[3]

Also used as a catalytic photoreductant in:

• The synthesis of thioethers from aryl chlorides & alcohols[4]

Leistungsmerkmale und Vorteile

1-Methylindoline-2-thione is an affordable indole thiolate that is useful in general synthesis as well as the transition-metal free photocatalytic reduction of a range of strong polar C-F, C-O and C-Cl bonds.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3