668001

Silber-Bis(trifluormethansulfonyl)imid

97%

• Synonym(e): Silver bis(trifluoromethanesulfonyl)amide, Silver bis(trifluoromethylsulfonyl)amide, Silver triflimide
• Empirische Formel (Hill-System): C₂AgF₆NO₄S₂
• CAS-Nummer: 189114-61-2
• Molekulargewicht: 388.01
• MDL-Nummer: MFCD08457644
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24884953
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• Form: solid
• Eignung der Reaktion: core: silver; reagent type: catalyst
• mp (Schmelzpunkt): 248.8 °C
• SMILES String: FC(F)(F)S(=O)(=O)N([Ag])S(=O)(=O)C(F)(F)F
• InChI: 1S/C2F6NO4S2.Ag/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1
• InChIKey: HSYLTRBDKXZSGS-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Silver bis(trifluoromethanesulfonyl)imide is a silver-based salt that is widely used as a catalyst in organic synthesis. It is used in the C₃ regioselective alkylation of indole derivatives via conjugated addition type reactions with α, β-enones. It is also used as a p-type dopant for efficient and stable solid-state dye-sensitized and perovskite solar cells.

Anwendung

Gold Catalysts — 21st Century ′Gold Rush′

Sicherheitshinweise

• Piktogramme: GHS05
• Signalwort: Danger
• H-Sätze: H314
• P-Sätze: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Gefahreneinstufungen: Skin Corr. 1B
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges