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901409

Sigma-Aldrich

[Ir(dF(Me)ppy)2(dtbbpy)]PF6

Synonym(e):

Iridium(III)-bis[2-(2,4-difluorphenyl)-5-methylpyridin-N,C20]-4,40-di-tert-butyl-2,20-bipyridin-hexafluorphosphat

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100 MG
295,00 €

295,00 €

Versandbereit am23. April 2025Details

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100 MG
295,00 €

About This Item

Empirische Formel (Hill-System):
C42H40F10IrN4P
CAS-Nummer:
1335047-34-1
Molekulargewicht:
1013.97
MDL-Nummer:
MFCD31619196
UNSPSC-Code:
12161600
NACRES:
NA.22

295,00 €

Versandbereit am23. April 2025Details

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Form

solid

Qualitätsniveau

100

Eignung der Reaktion

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

Photokatalysatoraktivierung

450 nm

InChIKey

XAJPUJWOMJJPNU-UHFFFAOYSA-N

Verwandte Kategorien

Anwendung

[Ir(dF(Me)ppy)2(dtbbpy)]PF6 ist ein Photokatalysator und ermöglicht die Hydroaminierung von Olefinen sowie die decarboxylierende Arylierung und Vinylierung von Carboxylsäuren mittels Metall-/Photoredox-Katalyse.

Das Produkt kann mit unserem Sortiment von Photoreaktoren verwendet werden: Einschließlich Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Sonstige Hinweise

Catalytic intermolecular hydroaminations of unactivated olefins with secondary alkyl amines

Merging photoredox and nickel catalysis: Decarboxylative cross-coupling of carboxylic acids with vinyl halides

Enhanced luminescent iridium(III) complexes bearing aryltriazole cyclometallated ligands

Site-Selective and Stereoselective C-H Alkylations of Carbohydrates via Combined Diarylborinic Acid and Photoredox Catalysis

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Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
MKCQ2750
MKCJ5323
MKCK6936

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Die Dokumentenbibliothek aufrufen

Victoria Dimakos et al.
Journal of the American Chemical Society, 141(13), 5149-5153 (2019-03-23)
Diphenylborinic acid serves as a cocatalyst for site- and stereoselective C-H alkylation reactions of carbohydrates under photoredox conditions using quinuclidine as the hydrogen atom transfer mediator. Products arising from selective abstraction of the equatorial hydrogens of cis-1,2-diol moieties, followed by
Strongly Blue Luminescent Cationic Iridium(III) Complexes with an Electron-Rich Ancillary Ligand: Evaluation of Their Optoelectronic and Electrochemiluminescence Properties.
Ladouceur S, et al.
European Journal of Inorganic Chemistry, 2013(30), 5329-5343 (2013)
Andrew J Musacchio et al.
Science (New York, N.Y.), 355(6326), 727-730 (2017-02-18)
The intermolecular hydroamination of unactivated alkenes with simple dialkyl amines remains an unsolved problem in organic synthesis. We report a catalytic protocol for efficient additions of cyclic and acyclic secondary alkyl amines to a wide range of alkyl olefins with
Correlating electronic structures to electrochemiluminescence of cationic Ir complexes.
Swanick KN, et al.
Royal Society of Chemistry Advances, 43, 19961-19964 (2013)
Adam Noble et al.
Journal of the American Chemical Society, 137(2), 624-627 (2014-12-19)
Decarboxylative cross-coupling of alkyl carboxylic acids with vinyl halides has been accomplished through the synergistic merger of photoredox and nickel catalysis. This new methodology has been successfully applied to a variety of α-oxy and α-amino acids, as well as simple
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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 Antwort

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 Antwort

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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