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688614

Sigma-Aldrich

Basolith® C 300

greener alternative

produced by BASF

Synonym(e):

Cu-BTC MOF, Kupfer-benzol-1,3,5-tricarboxylat

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About This Item

Empirische Formel (Hill-System):
C18H6Cu3O12
Molekulargewicht:
604.87
MDL-Nummer:
MFCD10567003
UNSPSC-Code:
26111700
PubChem Substanz-ID:
329761179
NACRES:
NA.23

Qualität

produced by BASF

Qualitätsniveau

100

Form

solid

Eignung der Reaktion

reagent type: catalyst
core: copper

Grünere Alternativprodukt-Eigenschaften

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Oberflächenbereich

1500-2100 m2/g

Partikelgrößenverteilung

15.96 μm (D50)

Schüttdichte

0.35 g/cm3

Grünere Alternativprodukt-Kategorie

, Enabling

SMILES String

O=C(O[Cu]OC(=O)c1cc2cc(c1)C(=O)O[Cu]OC2=O)c3cc4cc(c3)C(=O)O[Cu]OC4=O

InChI

1S/2C9H6O6.3Cu/c2*10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15;;;/h2*1-3H,(H,10,11)(H,12,13)(H,14,15);;;/q;;3*+2/p-6

InChIKey

NOSIKKRVQUQXEJ-UHFFFAOYSA-H

Allgemeine Beschreibung

MOF (metal organic framework)
Basolite®C 300 is a metal organic framework (MOF). It is a crystallized hybrid porous solid built up from inorganic subunits, which are connected to organic linkers such as carboxylates or phosphonates. It is a commercialized sorbent that has the structure of HKUST-1.[1][2]
HKUST-1 is also known as MOF-199, Cu-BTC and Basolite(TM) C300. HKUST-1 is a blue cubic crystal of copper based ultramicroporous metal framework (MOF). It is prepared by solvothermal method. It could have a surface area of nearly 2200 m2/g2.[3]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Anwendung

Basolite®C 300 can be used in the adsorption of carbon dioxide, carbon monoxide, and liquid absorption of dibenzothiopene.[1][4]
Used for gas adsorption (carbon dioxide, nitrogen, oxygen, hydrogen gas), catalysis, and separations

Sonstige Hinweise

kann bei 200°C reaktiviert werden (Vakuum)

Rechtliche Hinweise

Basolite is a registered trademark of BASF SE

Piktogramme

Skull and crossbonesEnvironment
GHS06,GHS09

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2

Lagerklassenschlüssel

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Zulassungslistungen

Zulassungslistungen werden hauptsächlich für chemische Produkte erstellt. Für nicht-chemische Produkte können hier nur begrenzte Angaben gemacht werden. Kein Eintrag bedeutet, dass keine der Komponenten gelistet ist. Es liegt in der Verantwortung des Benutzers, die sichere und legale Verwendung des Produkts zu gewährleisten.

EU REACH Annex XVII (Restriction List)

CAS No.

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
BCCJ0231
BCCG1834
BCCC1256
BCBZ6293
BCBW8681

Die passende Version wird nicht angezeigt?

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Sigma-Aldrich

F300

Eisen(III)-Acetylacetonat

Jiang, D.; et al.
Catalysis Communications, 12, 602-605 (2011)
Ayanjeet Ghosh et al.
The journal of physical chemistry letters, 8(21), 5325-5330 (2017-10-13)
We report here the first mesoscale characterization of solvent environments in the metal-organic framework (MOF) Cu
Yang, H.; et al.
Microporous Mater., 143, 37-45 (2011)
Nak Cheon Jeong et al.
Journal of the American Chemical Society, 134(1), 51-54 (2011-12-14)
HKUST-1, a metal-organic framework (MOF) material containing Cu(II)-paddlewheel-type nodes and 1,3,5-benzenetricarboxylate struts, features accessible Cu(II) sites to which solvent or other desired molecules can be intentionally coordinated. As part of a broader investigation of ionic conductivity in MOFs, we unexpectedly
Dan Ping Wang et al.
Journal of colloid and interface science, 529, 265-272 (2018-06-17)
A mesoporous octahedral copper oxide@titania (CuO/TiO2) composites with core-shelled structure have been successfully fabricated via a facile and cost-effective approach, which involves two main steps: the creation of homogeneous TiO2 shell onto the octahedral Cu-based metal-organic frameworks (MOFs) template and
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Metal Organic Frameworks (MOFs)

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

Metal-Organic Frameworks in Energy

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

Fragen

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 Antwort

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 Antwort

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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