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Wichtige Dokumente
668729
Diethylzink
packaged for use in deposition systems
Synonym(e):
DEZ, Zinkdiethyl
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About This Item
Lineare Formel:
(C2H5)2Zn
CAS-Nummer:
Molekulargewicht:
123.51
Beilstein:
3587207
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.23
Preise und Verfügbarkeit sind derzeit nicht verfügbar.
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Form
liquid
Brechungsindex
n20/D 1.498 (lit.)
bp
117 °C (lit.)
mp (Schmelzpunkt)
−28 °C (lit.)
Dichte
1.205 g/mL at 25 °C (lit.)
SMILES String
CC[Zn]CC
InChI
1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;
InChIKey
HQWPLXHWEZZGKY-UHFFFAOYSA-N
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Allgemeine Beschreibung
Atomic number of base material: 30 Zinc
Anwendung
Reacted with water in a low temperature (<200°C) atomic layer deposition of polycrystalline ZnO layers displaying exciton photoluminescence at room temperature.[1]
Signalwort
Danger
H-Sätze
Gefahreneinstufungen
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1
Zusätzliche Gefahrenhinweise
Lagerklassenschlüssel
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Journal of Applied Physics, 103, 033515-033515 (2008)
Abu Bakar Md et al.
Chemical & pharmaceutical bulletin, 56(1), 57-59 (2008-01-08)
N-Heterocyclic carbenes (NHCs) were generated in-situ from imidazolium and imidazolinium salts by deprotonation of C-2 hydrogen and were used as ligands in the copper-catalyzed addition of diethylzinc to N-sulfonylimines. The copper-NHC complexes were shown to possess an efficient ligand acceleration
Efficient chirality switching in the addition of diethylzinc to aldehydes in the presence of simple chiral alpha-amino amides.
M Isabel Burguete et al.
Angewandte Chemie (International ed. in English), 46(47), 9002-9005 (2007-09-26)
Isabelle Bonnaventure et al.
The Journal of organic chemistry, 73(16), 6330-6340 (2008-07-22)
The hemilabile ligand Me-DuPHOS(O) 2 has proven to be a successful ligand for the copper-catalyzed addition of diethylzinc to N-phosphinoylimines. The corresponding alpha-chiral amines were obtained in high yields (80-98%) and enantiomeric ratios (19.0:1 to 99.0:1 er). Furthermore, this Cu*
Vincent Coeffard et al.
Organic & biomolecular chemistry, 7(8), 1723-1734 (2009-04-04)
The straightforward preparation of new modular oxazoline-containing bifunctional catalysts is reported employing a microwave-assisted Buchwald-Hartwig aryl amination as the key step. Covalent attachment of 2-(o-aminophenyl)oxazolines and pyridine derivatives generated in good-to-high yields a series of ligands in two or three
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