4-tert-Butylbenzenethiol can be used to synthesize Pd–thiolate complex by coordinating with Pd2+.The reduction of this complex forms ultrasmall palladium nanoclusters.
Gold-copper alloys have rich forms. Here we report an atomically resolved [Au52Cu72(p-MBT)55]+Cl- nanoalloy (p-MBT = SPh-p-CH3). This nanoalloy exhibits unusual structural patterns. First, two Cu atoms are located in the inner 7-atom decahedral kernel (M7, M = Au/Cu). The M7 kernel is then enclosed
Chemistry, an Asian journal, 15(23), 4077-4081 (2020-10-14)
We report the single-crystal synthesis of a chlorine-centered bimetallic cluster, Cl@Ag22 Au6 (4-TBBT)28 (PPh4 ), which bears a quatrefoil-structured Cl@Ag22 (SR)16 core studded by six Au(SR)2 staples showing a quasi Td symmetry. This cluster bears 28 metal atoms and 28
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 16(7), 1043-1048 (2017-05-10)
Under the irradiation of red light (690 nm), quinones were converted to hydroquinones by thiols in the presence of metallophthalocyanines. The reaction proceeded via the charge separation between the triplet state of phthalocyanine and the quinone. The product determining step
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