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Merck

577065

Sigma-Aldrich

Polypyrrol

undoped, extent of labeling: ~20 wt. % loading, composite with carbon black

Synonym(e):

Ppy

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About This Item

CAS-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352103
NACRES:
NA.23

Form

solid

Kennzeichnungsgrad

~20 wt. % loading

Leitfähigkeit

~8.5 S/cm

Löslichkeit

H2O: insoluble
organic solvents: insoluble

InChI

1S/C4H5N/c1-2-4-5-3-1/h1-5H

InChIKey

KAESVJOAVNADME-UHFFFAOYSA-N

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Allgemeine Beschreibung

Polypyrrole (PPy) is a conductive and highly stable polymer. It may be prepared by a standard electrochemical technique. PPy may also be prepared by reacting ß-napthalene sulfonic acid (NSA) and ammonium peroxo-disulphate in aqueous medium. The charges on the surfaces can be easily modified by doping the polymer during its synthesis.Solubility and conductivity measurements of PPy doped with camphor sulfonic and dodecyl benzene sulfonic acid has been reported. Electrosensitivity and lower oxidation potential of PPy make it potentially useful for drug delivery, chemical sensors, batteries, ion selective electrodes, biosensor and biochemistry research.5,

Anwendung

PPy may be used to prepare cobalt based electrocatalyst for anion exchange membrane fuel cells.
Conducting polymer.
Conductive additive for thermoplasitics and thermosets.

Verpackung

Packaged in glass bottles

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


Analysenzertifikate (COA)

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XAFS analysis of unpyrolyzed CoPPyC oxygen reduction catalysts for anion-exchange membrane fuel cells (AMFC).
Asazawa K, et al.
Electrochemical Society Transactions, 33(1), 1751-1755 (2010)
In Situ XAFS and HAXPES Analysis and Theoretical Study of Cobalt Polypyrrole Incorporated on Carbon (CoPPyC) Oxygen Reduction Reaction Catalysts for Anion-Exchange Membrane Fuel Cells
Asazawa K, et al.
The Journal of Physical Chemistry C, 118(44), 25480-25486 (2014)
Anion-exchange membrane fuel cells: Dual-site mechanism of oxygen reduction reaction in alkaline media on cobalt- polypyrrole electrocatalysts.
Olson TS, et al.
The Journal of Physical Chemistry C, 114(11), 5049-5059 (2010)
Lijia Chen et al.
ACS applied materials & interfaces, 5(6), 2047-2052 (2013-03-02)
Herein graphene quantum dot (GQD), a graphene material with lateral dimension less than 100 nm, is explored to dope PPy on F-doped tin oxide glass as an efficient counter electrode for high-performance dye-sensitized solar cells (DSSCs). The GQDs-doped PPy film
Gusphyl A Justin et al.
Conference proceedings : ... Annual International Conference of the IEEE Engineering in Medicine and Biology Society. IEEE Engineering in Medicine and Biology Society. Annual Conference, 2012, 1206-1209 (2013-02-01)
An electronically-controlled drug delivery system (eDDS) for the on-demand release of anti-inflammatory, anti-microbial and analgesic agents to aid in wound healing is currently under development. The loading of several drugs into conductive polymer films and their subsequent on-demand, controlled release

Artikel

Self-healing soft electronic materials offer potential cost savings and reduced electronic waste.

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