473006

(1S,4S)-(+)-2,5-Diazabicyclo[2.2.1]heptan

97%

• Synonym(e): (1S,4S)-2,5-Diazabicyclo[2.2.1]heptan -dihydrobromid
• Empirische Formel (Hill-System): C₅H₁₀N₂ · 2HBr
• CAS-Nummer: 132747-20-7
• Molekulargewicht: 259.97
• MDL-Nummer: MFCD08272741
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24870860
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• Optische Aktivität: [α]23/D +22°, c = 1 in H₂O
• mp (Schmelzpunkt): 300 °C (dec.) (lit.)
• SMILES String: Br.Br.C1N[C@@H]2CN[C@H]1C2
• InChI: 1S/C5H10N2.2BrH/c1-4-2-6-5(1)3-7-4;;/h4-7H,1-3H2;2*1H/t4-,5-;;/m0../s1
• InChIKey: ISYQWKOXKGJREA-RSLHMRQOSA-N

Beschreibung

Anwendung

(1S,4S)-(+)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide can be used as:

• A starting material for the synthesis of chiral diazabicyclic ligands, applicable in the preparation of dicopper(II) complexes.
• A precursor in the preparation of diazabicyclo[2.2.1]heptane derivatives as catalysts, which are applicable in the asymmetric catalysis reactions.
• An organocatalyst in Biginelli reaction of aromatic aldehydes with ethyl acetoacetate and urea.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable