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Sigma-Aldrich

Methanol-d3

99.8 atom % D

Synonym(e):

1,1,1-Trideuteromethanol, Methyl-d3-alkohol

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About This Item

Lineare Formel:
CD3OH
CAS-Nummer:
1849-29-2
Molekulargewicht:
35.06
Beilstein:
1732010
EG-Nummer:
217-435-9
MDL-Nummer:
MFCD00055877
UNSPSC-Code:
12142201
PubChem Substanz-ID:
24861211
NACRES:
NA.21

Isotopenreinheit

99.8 atom % D

Assay

99% (CP)

Form

liquid

Expl.-Gr.

5.5-36.5 % (lit.)

Methode(n)

NMR: suitable

Verunreinigungen

≤0.05% water
water

Brechungsindex

n20/D 1.327 (lit.)

bp

65 °C (lit.)

Dichte

0.867 g/mL at 25 °C (lit.)

Format

neat

Massenverschiebung

M+3

SMILES String

[2H]C([2H])([2H])O

InChI

1S/CH4O/c1-2/h2H,1H3/i1D3

InChIKey

OKKJLVBELUTLKV-FIBGUPNXSA-N

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Allgemeine Beschreibung

Methanol-d3 is a deuterated NMR solvent that is useful in NMR-based research and analyses.

Anwendung

Methanol-d3 may be used in the preparation of [Al(CH3)2OCD3]3 by reacting with trimethylaluminum for use in spectroscopic analysis of dialkylaluminum alkoxides and the trialkylaluminum-ether complex.

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Zubehör

Produkt-Nr.
Beschreibung
Preisangaben

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

Zielorgane

Eyes,Central nervous system

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 2

Flammpunkt (°F)

51.8 °F - closed cup

Flammpunkt (°C)

11 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves

Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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Władysław Wrzeszcz et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 188, 349-354 (2017-07-29)
Recently, we demonstrated the presence of microheterogeneity in binary mixtures of unlike alcohols. [RSC Adv. 2016, 6, 37195-37202] The aim of this work was examination if this phenomenon occurs also in the mixture of very similar alcohols like CH
Thierry Jauffrais et al.
Marine drugs, 10(6), 1360-1382 (2012-07-24)
Azaspiracid (AZA) poisoning has been reported following consumption of contaminated shellfish, and is of human health concern. Hence, it is important to have sustainable amounts of the causative toxins available for toxicological studies and for instrument calibration in monitoring programs
Paweł Tomza et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 197, 88-94 (2018-02-06)
Here we report ATR-IR spectroscopic study on the separation at a molecular level (microheterogeneity) and the degree of deviation of H2O/CH3OH and H2O/CD3OH mixtures from the ideal mixture. Of particular interest is the effect of isotopic substitution in methyl group
Spectroscopic Studies of Dialkylaluminum Alkoxides and the Trialkyl-aluminum-Ether Complex. II. Assignments of Observed Frequencies
Tarao, R
Bulletin of the Chemical Society of Japan, 39(10), 2126-2132 (1966)
Jason S Adams et al.
Science (New York, N.Y.), 371(6529), 626-632 (2021-02-06)
Solvent molecules influence the reactions of molecular hydrogen and oxygen on palladium nanoparticles. Organic solvents activate to form reactive surface intermediates that mediate oxygen reduction through pathways distinct from reactions in pure water. Kinetic measurements and ab initio quantum chemical

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