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Merck

287717

Sigma-Aldrich

Boranammoniak-Komplex

greener alternative

technical grade, 90%

Synonym(e):

Amin-Trihydrobor, Borazan

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About This Item

Lineare Formel:
H3N · BH3
CAS-Nummer:
Molekulargewicht:
30.87
MDL-Nummer:
UNSPSC-Code:
26111700
PubChem Substanz-ID:
NACRES:
NA.22

Qualität

technical grade

Assay

90%

Form

solid

Eignung der Reaktion

reagent type: reductant

Grünere Alternativprodukt-Eigenschaften

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Grünere Alternativprodukt-Kategorie

SMILES String

B.N

InChI

1S/BH3.H3N/h2*1H3

InChIKey

WZMUUWMLOCZETI-UHFFFAOYSA-N

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Allgemeine Beschreibung

Ammonia borane, also known as borazane has high hydrogen content (about 20% mass). Thermal decomposition of borazane takes place in the temperature range of 350-410K accompanied by hydrogen release and heat evolution. It may find use as a hydrogen source in fuel cells in the future.
Borane-ammonia complex is a novel material, where ammonia is tightly bound to a ligand through all four of its atoms. It is a donor-acceptor complex that is formed by electron donation from a Lewis base (NH3) to a Lewis acid (BH3). It shows a B-N bond distance of 1.564 Å.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Anwendung

Mild, efficient, and stereoselective reducing agent for aldehydes and ketones in protic or nonprotic media.

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Persönliche Schutzausrüstung

Eyeshields, Gloves


Analysenzertifikate (COA)

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Die Dokumentenbibliothek aufrufen

William C Ewing et al.
Journal of the American Chemical Society, 133(42), 17093-17099 (2011-10-04)
Studies of the activating effect of Verkade's base, 2,8,9-triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane (VB), on the rate and extent of H(2) release from ammonia borane (AB) have led to the syntheses and structural characterizations of three anionic aminoborane chain-growth products that provide direct support
X. Yang, et al.,
Tetrahedron, 67, 7121-7127 (2011)
Weng, B.; et al.
International Journal of Hydrogen Energy, 36, 10870-10870 (2011)
Gang Hee Han et al.
ACS nano, 7(11), 10129-10138 (2013-11-05)
Graphene-boron nitride monolayer heterostructures contain adjacent electrically active and insulating regions in a continuous, single-atom thick layer. To date structures were grown at low pressure, resulting in irregular shapes and edge direction, so studies of the graphene-boron nitride interface were
Thermal decomposition of B-N-H compounds investigated by using combined thermoanalytical methods.
Baitalow F, et al.
Thermochimica Acta, 391(1), 159-168 (2002)

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