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Dokumente

252166

Sigma-Aldrich

5,10,15,20-Tetraphenyl-21H,23H-porphinzink

Synonym(e):

TPP, Zink TPP

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About This Item

Empirische Formel (Hill-System):
C44H28N4Zn
CAS-Nummer:
14074-80-7
Molekulargewicht:
678.11
MDL-Nummer:
MFCD00012155
UNSPSC-Code:
12352103
PubChem Substanz-ID:
24855186
NACRES:
NA.23

λmax

418 nm

Leistung von OLED-Bauelementen

ITO/TPD/Alq3:TPP (3%)/Alq3/Mg:Ag

  • Color: red
  • Max. Luminance: 42 V
  • Max. EQE: 0.07 %

SMILES String

[Zn]1n2c3ccc2c(-c4ccccc4)c5ccc(n5)c(-c6ccccc6)c7ccc(c(-c8ccccc8)c9ccc(n9)c3-c%10ccccc%10)n17

InChI

1S/C44H28N4.Zn/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;/h1-28H;/q-2;+2/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;

InChIKey

XPVVGUHKLPZAEN-DAJBKUBHSA-N

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Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)

Analysenzertifikate (COA)

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V L Schlegel et al.
Analytical chemistry, 63(3), 241-247 (1991-02-01)
The relationship between surface-enhanced resonance Raman scattering (SERRS) intensity and the rate of deposition during silver-island film preparation was examined, using zinc tetraphenylporphine (ZnTPP) as the adsorbate. The effect of the deposition rate on the optical properties of the films
H Kolarova et al.
Toxicology in vitro : an international journal published in association with BIBRA, 19(7), 971-974 (2005-08-03)
The basis of photodynamic therapy (PDT) is the phototoxicity resulting from co-action of light, sensitizer and oxygen. In this study we demonstrate in vitro phototoxicity measurement on G361 cell lines using ZnTPPS(4) sensitizer bound to cyclodextrin hpbetaCD. We have proved
Martin Kullmann et al.
Physical chemistry chemical physics : PCCP, 14(22), 8038-8050 (2012-05-03)
We report on a comprehensive transient absorption study with β,β'-linked bis[tetraphenylporphyrinato-zinc(II)] and its corresponding monomer, covering the ultrafast dynamics from femtoseconds up to several microseconds. By exciting these porphyrins either to their first (S(1)) or second (S(2)) electronically excited states
Vijaykumar S Ijeri et al.
Langmuir : the ACS journal of surfaces and colloids, 24(3), 1070-1079 (2008-01-05)
Active spatial and temporal modulation of domains of singlet oxygen activity is demonstrated using electrochemical tools. Using singlet oxygen microscopy in photosensitized experiments, it is shown that singlet oxygen concentrations around an ultramicroelectrode can be controlled by applying a bias
Suyi Zhang et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 88, 137-143 (2012-01-10)
The molecular interactions of 5,10,15,20-tetraphenylporphine zinc (ZnTPP) and 5,10,15,20-tetraphenyl-21H,23H-porphine cobalt(II) (CoTPP) with dimethyl methylphosphonate (DMMP) have been investigated by absorption/absorption difference spectroscopy. The interactions between the metalloporphyrins and DMMP change the absorbance characteristics of the porphyrins resulted from the formation
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