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203106

Sigma-Aldrich

Cobalt(II)-nitrat Hexahydrat

99.999% trace metals basis

Synonym(e):

Salpetersäure Cobalt(II)-salz

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About This Item

Lineare Formel:
Co(NO3)2 · 6H2O
CAS-Nummer:
Molekulargewicht:
291.03
MDL-Nummer:
UNSPSC-Code:
12352302
PubChem Substanz-ID:
NACRES:
NA.23

Qualitätsniveau

Assay

99.999% trace metals basis

Form

crystals and lumps

Verunreinigungen

≤15.0 ppm Trace Metal Analysis

mp (Schmelzpunkt)

55 °C (lit.)

Anwendung(en)

battery manufacturing

SMILES String

O.O.O.O.O.O.[Co++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Co.2NO3.6H2O/c;2*2-1(3)4;;;;;;/h;;;6*1H2/q+2;2*-1;;;;;;

InChIKey

QGUAJWGNOXCYJF-UHFFFAOYSA-N

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Allgemeine Beschreibung

Cobalt(II) nitrate hexahydrate is an inorganic compound soluble in water. It is used as a precursor for the synthesis of cobalt-containing ceramic materials, such as cobalt ferrites and cobalt-doped titanium dioxide, which have magnetic, electrical, and photocatalytic properties. In addition, it finds use in electrochemical applications, such as in lithium-ion battery cathodes and fuel cell catalysts, due to the redox activity.

Anwendung

Cobalt(II) nitrate hexahydrate can be:      
  • Used as a precursor to synthesize nano-Co3O4 via direct thermal decomposition method for electrochemical water oxidation applications      
  • Used as a precursor to synthesize single-crystalline Co3O4 powders with controllable morphology for lithium-ion battery applications.      cobalt-containing nanomaterials, such as nano-Co3O4, with controlled size, shape, and morphology via sol-gel method.      
  • As a vital precursor to generate nickel-rich cathode materials (NMC, NCA) for lithium-ion batteries using co-precipitation process because of its simplicity, ease of scale-up, and ability to produce a homogeneous structure at the particle scale.

Cobalt(II) nitrate hexahydrate can be used as a:      
  • A starting material in the preparation of Co-based nanomaterials and Co complexes.      
  • A catalyst to synthesize 5-carboxanilide-dihydropyrimidinone derivatives via a three-component condensation reaction.     
  • A dopant to prepare LaCr1−xCoxO3 solid-solution ceramics for high temperature applications.

Leistungsmerkmale und Vorteile

  • High purity with trace metal analysis (=< 15 ppm) for 32 elements, suitable for batteries.     
  • High water solubility ideal for synthesizing composites for various applications.
  • Low ppm levels of metal ions including Al, K, Na, Mg, Cu, Co, etc.

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 2 Inhalation

Zielorgane

Lungs

Lagerklassenschlüssel

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Analysenzertifikate (COA)

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Yonghoon Hong et al.
Scientific reports, 8(1), 7469-7469 (2018-05-12)
We have developed a highly stable and magnetically recyclable yolk-shell nanocatalyst for catalytic reduction of nitroaromatics. This nanocatalyst is composed of a ~13 nm Au nanoparticle encapsulated in a hollow mesoporous carbon (hmC) shell with a diameter of ~120 nm and a
Massimiliano Aschi et al.
Journal of mass spectrometry : JMS, 44(7), 1038-1046 (2009-04-01)
The nature of the ionic species, formed by electrospray ionization (ESI) of Co(NO3)2/CH3OH solutions with a pair of aminoalcohols W and Y, has been investigated by mass spectrometric and computational methods. Collision induced dissociation (CID) of ions, formally corresponding to
William Buchmann et al.
Journal of mass spectrometry : JMS, 42(4), 517-526 (2007-02-27)
The electronebulization of a cobalt(II)/cysteine(Cys) mixture in water/methanol (50/50) produced mainly cobalt-cationized species. Three main groups of the Co-cationized species can be distinguished in the ESI-MS spectrum: (1) the cobalt complexes including the cysteine amino acid only (they can be
A time-resolved in situ quick-XAS investigation of thermal activation of Fischer-Tropsch silica-supported cobalt catalysts.
Jingping Hong et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(10), 2802-2805 (2012-02-07)
H H Chen et al.
Nucleic acids research, 10(11), 3561-3571 (1982-06-11)
Transient electric dichroism measurements have been used to observe the rotational relaxation times of 145 base pair fragments of poly (dGm5dC) and random sequence DNA to solution. From these the lengths of the fragments are calculated and the interbase pair

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