164569

Triphenylcarbenium-hexafluorophosphat

• Synonym(e): Tritylium-hexafluorophosphat, NSC 176018, Triphenylcarbenium-hexafluorophosphat, Triphenylmethyl-hexafluorophosphat
• Lineare Formel: (C₆H₅)₃C(PF₆)
• CAS-Nummer: 437-17-2
• Molekulargewicht: 388.29
• Beilstein: 4344297
• EG-Nummer: 207-112-0
• MDL-Nummer: MFCD00013121
• UNSPSC-Code: 12352101
• PubChem Substanz-ID: 24850084
• NACRES: NA.22

Eigenschaften

• Form: solid
• Qualitätsniveau: 200
• mp (Schmelzpunkt): ~150 °C (dec.) (lit.)
• Lagertemp.: 2-8°C
• SMILES String: F[P-](F)(F)(F)(F)F.c1ccc(cc1)[C+](c2ccccc2)c3ccccc3
• InChI: 1S/C19H15.F6P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7(2,3,4,5)6/h1-15H;/q+1;-1
• InChIKey: IBTFOFOFRZKIJU-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactant of reagent involved in:

• Si-H and Si-Si bond activeation at Pt of neutral and cationic silyl Pt bisphosphine complexes
• Investigations of interactions with chromium acetylacetonate nitride mononuclear complexes
• Synthesis of "push-pull" tropylium-fused aminoporphyrazine
• Preparation of cycloheptatrienyl and tropylium calix[4]arenes
• Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst
• Double ring-opening polyaddition of spiro orthoesters

Sicherheitshinweise

• Piktogramme: GHS05
• Signalwort: Danger
• H-Sätze: H314
• P-Sätze: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Gefahreneinstufungen: Skin Corr. 1B
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges