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Phenylmethansulfonylchlorid
98%
Synonym(e):
α-Toluolsulfonylchlorid
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About This Item
Lineare Formel:
C6H5CH2SO2Cl
CAS-Nummer:
Molekulargewicht:
190.65
Beilstein:
972806
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
Empfohlene Produkte
Assay
98%
Form
solid
mp (Schmelzpunkt)
92-94 °C (lit.)
Funktionelle Gruppe
phenyl
SMILES String
ClS(=O)(=O)Cc1ccccc1
InChI
1S/C7H7ClO2S/c8-11(9,10)6-7-4-2-1-3-5-7/h1-5H,6H2
InChIKey
OAHKWDDSKCRNFE-UHFFFAOYSA-N
Allgemeine Beschreibung
Phenylmethanesulfonyl chloride is an aliphatic sulfonyl chloride. It reacts with triethylamine in methylene chloride or ether to yield trans-stilbene and cis diphenylethylene sulfone.[1] Its reaction with 1,1-bis(diethylamino)ethane has been studied.[2] Addition of phenylmethanesulfonyl chloride to 1,3-diphenyl-2-pyrrolidinopropene in the presence of water was studied.[3]
Signalwort
Danger
H-Sätze
Gefahreneinstufungen
Skin Corr. 1B
Lagerklassenschlüssel
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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THE REACTION OF PHENYLMETHANESULFONYL CHLORIDE WITH TERTIARY AMINES: FORMATION OF GEOMETRICAL ISOMERS ABOUT A CARBON-SULFUR DOUBLE BOND.
King JF and Durst T.
Canadian Journal of Chemistry, 44(7), 819-828 (1966)
Snehal Nirgude et al.
Molecules (Basel, Switzerland), 25(19) (2020-10-04)
Curcumin is known for its anticancer and migrastatic activity in various cancers, including breast cancer. Newer curcumin derivatives are being explored to overcome limitations of curcumin like low bioavailability, stability, and side effects due to its higher dose. In this
Addition of Aliphatic Sulfonyl Chlorides to Enamines. Formation of Acyclic Products.
Looker JJ.
The Journal of Organic Chemistry, 31(9), 2973-2976 (1966)
The reaction of 1,1-bs(diethylamino)ethene with phenylmethanesulfonyl chloride.
W E Truce et al.
The Journal of organic chemistry, 30(1), 71-74 (1965-01-01)
Preeti Verma et al.
The FEBS journal, 284(24), 4233-4261 (2017-10-25)
The 5-aminoimidazole-4-carboxamide ribonucleotide (AICAR) transformylase/inosine monophosphate (IMP) cyclohydrolase (ATIC) catalyzes final two steps of purine nucleotide de novo biosynthetic pathway. This study reports the characterization of ATIC from Staphylococcus lugdunensis (SlugATIC). Apart from kinetic analysis and a detailed biophysical characterization
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