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  • "Carba" peptide bond surrogates. Different approaches to Gly-psi(CH2-CH2)-D,L-Xaa pseudo-dipeptide units.

"Carba" peptide bond surrogates. Different approaches to Gly-psi(CH2-CH2)-D,L-Xaa pseudo-dipeptide units.

International journal of peptide and protein research (1992-03-01)
M Rodriguez, A Heitz, J Martinez
ANOTACE

Racemic "carba" pseudo-dipeptide units such as Gly-psi(CH2-CH2)-D,L-Xaa were obtained either through the Horner-Emmons condensation of N-tert.-butyloxycarbonyl-beta alaninal with the appropriate substituted triethyl phosphonacetate, or from commercially available 3-carbethoxy-2-piperidone.

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Sigma-Aldrich
Triethyl phosphonoacetate, purum, ≥97.0% (GC)
Sigma-Aldrich
Triethyl phosphonoacetate, 98%