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T61301

Triethyl phosphonoacetate

98%

Synonyma:

(Diethoxyphosphinyl)acetic acid ethyl ester, Diethyl ethoxycarbonylmethylphosphonate, NSC 13898, NSC 16128, Triethyl carboxymethylphosphonate

pro zobrazení organizačních a smluvních cen.

Vybrat velikost

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Vám/Skladová položkaDostupnostCena
25 g
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1 240,00 Kč
100 g
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2 980,00 Kč

O této položce

Lineární vzorec:
(C2H5O)2P(O)CH2CO2C2H5
Číslo CAS:
Molekulová hmotnost:
224.19
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-757-6
Beilstein/REAXYS Number:
1343714
MDL number:
Assay:
98%

1 240,00 Kč


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Quality Segment

assay

98%

reaction suitability

reaction type: C-C Bond Formation

refractive index

n20/D 1.431 (lit.)

bp

142-145 °C/9 mmHg (lit.)

density

1.13 g/mL at 25 °C (lit.)

SMILES string

CCOC(=O)CP(=O)(OCC)OCC

InChI

1S/C8H17O5P/c1-4-11-8(9)7-14(10,12-5-2)13-6-3/h4-7H2,1-3H3

InChI key

GGUBFICZYGKNTD-UHFFFAOYSA-N

Application

Reactant involved in:
  • Horner-Wadsworth-Emmons reactions
  • Intramolecular Heck-type cyclization and isomerizations
  • Tsuji-Trost type reactions
  • Intramolecular aryne-ene reactions
  • Synthesis of aldehydes
Horner-Emmons-Wadsworth reagent recently used in the synthesis of chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.

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1 of 1

Tato položka
79525T79758158763
assay

98%

assay

≥97.0% (GC)

assay

98%

assay

97%

reaction suitability

reaction type: C-C Bond Formation

reaction suitability

reaction type: C-C Bond Formation

reaction suitability

reaction type: C-C Bond Formation

reaction suitability

reaction type: C-C Bond Formation

refractive index

n20/D 1.431 (lit.)

refractive index

n20/D 1.431 (lit.), n20/D 1.432

refractive index

n20/D 1.437 (lit.)

refractive index

n20/D 1.433 (lit.)

bp

142-145 °C/9 mmHg (lit.)

bp

142-145 °C/9 mmHg (lit.)

bp

118 °C/0.85 mmHg (lit.), 265-268 °C (lit.)

bp

127-131 °C/9 mmHg (lit.)

density

1.13 g/mL at 25 °C (lit.)

density

1.13 g/mL at 25 °C (lit.)

density

1.125 g/mL at 25 °C (lit.)

density

1.145 g/mL at 25 °C (lit.)

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100


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pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Skladovací třída

10 - Combustible liquids

wgk

WGK 2

flash_point_f

221.0 °F - closed cup

flash_point_c

105 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)



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Lot/Batch Number

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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