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Supelco

4,4′,4″,4″′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonic acid)

for spectrophotometric det. of transition metals, ≥95.0%

Synonyma:

meso-Tetraphenylporphine-4,4′,4″,4″′-tetrasulfonic acid

Přihlásitk zobrazení cen stanovených pro organizaci a smluvních cen


About This Item

Empirický vzorec (Hillův zápis):
C44H30N4O12S4
Číslo CAS:
Molekulová hmotnost:
934.99
Beilstein/REAXYS Number:
4227566
MDL number:
UNSPSC Code:
12000000
PubChem Substance ID:
NACRES:
NA.21

Quality Level

assay

≥95.0% (HPLC)
≥95.0%

form

powder

quality

for spectrophotometric det. of transition metals

technique(s)

UV/Vis spectroscopy: suitable

impurities

~9% water

SMILES string

OS(=O)(=O)c1ccc(cc1)-c2c3ccc(n3)c(-c4ccc(cc4)S(O)(=O)=O)c5ccc([nH]5)c(-c6ccc(cc6)S(O)(=O)=O)c7ccc(n7)c(-c8ccc(cc8)S(O)(=O)=O)c9ccc2[nH]9

InChI

1S/C44H30N4O12S4/c49-61(50,51)29-9-1-25(2-10-29)41-33-17-19-35(45-33)42(26-3-11-30(12-4-26)62(52,53)54)37-21-23-39(47-37)44(28-7-15-32(16-8-28)64(58,59)60)40-24-22-38(48-40)43(36-20-18-34(41)46-36)27-5-13-31(14-6-27)63(55,56)57/h1-24,45,48H,(H,49,50,51)(H,52,53,54)(H,55,56,57)(H,58,59,60)/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

InChI key

PBHVCRIXMXQXPD-LWQDQPMZSA-N

Application

4,4′,4′′,4′′′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonic acid) [tetrasodium salt hydrate, TPPS] has been used in preparing Co–Al LDH/Fe(III)-TPPS film modified electrode; for demonstrating reversible redox peak attribution to Co(III)/Co(II), with iron(III) porphyrin; making it mediator for electron transfer.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Analysis Note

max. Absorption (in Methanol): 412-416 nm

Other Notes

Reagent for the spectrophotometric determination of ultra trace amounts of transition metals; determination by capillary zone electrophoresis

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Osvědčení o analýze (COA)

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Navštívit knihovnu dokumentů

E Collini
Physical chemistry chemical physics : PCCP, 14(11), 3725-3736 (2012-02-14)
In the search of new materials characterized by high two-photon absorption (TPA) efficiency, many efforts have been devoted to design chromophores with enhanced TPA responses progressively moving from linear chromophores such as dipoles and quadrupoles toward multimeric complex molecular architectures.
N Micali et al.
Nature chemistry, 4(3), 201-207 (2012-02-23)
Many essential biological molecules exist only in one of two possible mirror-image structures, either because they possess a chiral unit or through their structure (helices, for example, are intrinsically chiral), but so far the origin of this homochirality has not
Layer-by-layer assembly of porphyrin/layered double hydroxide ultrathin film and its electrocatalytic behavior for H 2 O 2.
Shao, Mingfei, et al.
Electrochemical Communications, 12.8, 1077-1080 (2010)
Kalivarathan Divakar et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 27(1), 101-103 (2011-01-15)
Protein identification in polyacrylamide gel electrophoresis (PAGE) requires post-electrophoretic steps like fixing, staining and destaining of the gel, which are time-consuming and cumbersome. We have developed a method for direct visualization of protein bands in PAGE using tetrakis(4-sulfonato phenyl)porphyrin (TPPS)
H. Ishii, H. Tsuchiai
Analytical Sciences, 3, 229-229 (1987)

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