222488

N-(1-Naphthyl)ethylenediamine dihydrochloride

ACS reagent grade, >98%, solid

• Synonyma: 2-(1-Naphthylamino)ethylamine dihydrochloride
• Lineární vzorec: C₁₀H₇NHCH₂CH₂NH₂ · 2HCl
• Číslo CAS: 1465-25-4
• Molekulová hmotnost: 259.17
• NACRES: NA.21
• PubChem Substance ID: 24853334
• UNSPSC Code: 12352100
• EC Number: 215-981-2
• MDL number: MFCD00012556
• Beilstein/REAXYS Number: 3707471
• Assay: >98%
• Form: solid

Vlastnosti

• Název produktu: N-(1-Naphthyl)ethylenediamine dihydrochloride, ACS reagent, >98%
• grade: ACS reagent
• Quality Segment: 200
• assay: >98%
• form: solid
• impurities: ≤5% water
• mp: 194-198 °C (dec.) (lit.)
• solubility: H₂O: passes test
• suitability: passes test for sensitivity to sulfanilamide
• functional group: amine
• SMILES string: Cl.Cl.NCCNc1cccc2ccccc12
• InChI: 1S/C12H14N2.2ClH/c13-8-9-14-12-7-3-5-10-4-1-2-6-11(10)12;;/h1-7,14H,8-9,13H2;2*1H
• InChI key: MZNYWPRCVDMOJG-UHFFFAOYSA-N

Popis

General description

N-(1-Naphthyl)ethylenediamine dihydrochloride (NEDA·2HCl) acts as donor molecule and forms charge transfer (CT) complexes with π-acceptors (quinol and picric acid), σ-acceptors (iodine) and vacant orbital acceptors (tin(IV) tetrachloride and zinc chloride). These complexes were investigated by positron annihilation lifetime spectroscopy (PAL).

Application

N-(1-Naphthyl)ethylenediamine dihydrochloride has been used for the preparation of staining solution for the visualization of the reaction product(s) of starch active enzymes, containing α-1, 4 linked and α-1, 6 linked glucose by thin layer chromatography. It has also been used in modified Saville and Griess assays.

N-(1-Naphthyl)ethylenediamine dihydrochloride may be used in the synthesis of 5-[1,2]dithiolan-3-yl-pentanoic acid [2-(naphthalene-1-ylamino)-ethyl]amide (DPAN) by reacting with (±)-1,2-dithiolane-3-pentanoic acid in the presence of N-(3-dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride and N-hydroxysuccinimide. The solution formed by dissolving N-(1-naphthyl)ethylenediamine dihydrochloride in sulfuric acid-methanol may be used as a reagent for the detection of sugars at nanoscale on thin-layer plates.

Coupling agent for the spectrophotometric determination of aminophenols, phenylenediamines, dinitroanilines, chloroanilines, thiols, and sulfonamides.

Solution of N-(1-naphthyl)ethylenediamine dihydrochloride in sulfuric acid-methanol may be employed for the quantitation of sugars.

Bezpečnostní informace

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319
• pcodes: P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2
• Skladovací třída: 11 - Combustible Solids
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves