14007

Potassium titanium oxide oxalate dihydrate

• Synonyma: Dipotassium oxodioxalatotitanate(IV) dihydrate, Oxotitanium potassium ethanedioate hydrate (1:2:2:2)
• Empirický vzorec (Hillův zápis): C₄K₂O₉Ti · 2H₂O
• Číslo CAS: 14402-67-6
• Molekulová hmotnost: 354.13
• EC Number: 238-475-3
• MDL number: MFCD00150592
• UNSPSC Code: 12161600
• PubChem Substance ID: 57647127
• NACRES: NA.22

Vlastnosti

• form: solid
• Quality Level: 100
• reaction suitability: core: titanium; reagent type: catalyst
• SMILES string: O.O.[K+].[K+].[O-]C(=O)C(=O)O[Ti](=O)OC(=O)C([O-])=O
• InChI: 1S/2C2H2O4.2K.2H2O.O.Ti/c2*3-1(4)2(5)6;;;;;;/h2*(H,3,4)(H,5,6);;;2*1H2;;/q;;2*+1;;;;+2/p-4
• InChI key: PGGRHIGITIPOBF-UHFFFAOYSA-J

Popis

General description

Potassium titanium oxide oxalate dihydrate is used as a catalyst in organic synthesis because of its excellent water solubility. It can be easily separated from the reaction mixture after the completion of the reaction.

Application

Potassium titanium oxide oxalate (PTO) dihydrate can be used as:

• A catalyst to synthesize chromene derivatives via three-component condensation reaction of aromatic aldehydes, malononitrile, and resorcinol/ naphthol.
• An electrolyte to functionalize the surface of aluminum alloy with TiO₂ layer by plasma electrolytic oxidation (PEO).

PTO can be used as a precursor to synthesize titanium dioxide (TiO₂) nanoparticles.

Bezpečnostní informace

• Storage Class: 13 - Non Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)