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86578

Tetraethyl orthosilicate

≥99.0% (GC)

Synonyma:

Orthosilicic acid tetraethyl ester, Silicon tetraethoxide, TEOS, Tetraethoxysilane, Tetraethoxysilicon(IV), Tetraethyl silicate

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Vám/SKUDostupnostCena
250 mL
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1 030,00 Kč
1 L
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3 140,00 Kč

O této položce

Lineární vzorec:
Si(OC2H5)4
Číslo CAS:
Molekulová hmotnost:
208.33
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-083-8
Beilstein/REAXYS Number:
1422225
MDL number:
Assay:
≥99.0% (GC)
Technique(s):
GC/GC: suitable
Bp:
168 °C (lit.)
Vapor pressure:
<1 mmHg ( 20 °C)

1 030,00 Kč


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vapor density

7.2 (vs air)

Quality Segment

vapor pressure

<1 mmHg ( 20 °C)

assay

≥99.0% (GC)

form

liquid

technique(s)

GC/GC: suitable

refractive index

n20/D 1.382 (lit.), n20/D 1.383

bp

168 °C (lit.)

density

0.933 g/mL at 20 °C (lit.)

SMILES string

CCO[Si](OCC)(OCC)OCC

InChI

1S/C8H20O4Si/c1-5-9-13(10-6-2,11-7-3)12-8-4/h5-8H2,1-4H3

InChI key

BOTDANWDWHJENH-UHFFFAOYSA-N

General description

Tetraethyl orthosilicate (TEOS) is an inorganic material that can be used as a silica source for the synthesis of silica-based materials such as silicon dioxide, silicon oxycarbides, silanol, siloxane polymer, and organosilicon thin films for a variety of applications. It can also be used in the synthesis of blended membranes, and the production of aerogel. Other applications include coatings for carpets and other objects.

Application

Commonly used as a precursor to prepare xerogel
Will interact with dodecylamine in the formation of intercalation compounds of H+-magadiite and used in a study of mixed-metal bioactive glasses.
Tetraethyl orthosilicate (TEOS) can be used:
  • As a reagent along with ferric chloride in the synthesis of dihydropyrimidinones.
  • As a modifier in fabrication of humidity sensing material, poly(2-acrylamido-2-methylpropane sulfonate) (poly-AMPS).
  • As a medium to synthesize triarylamines and diaryl ethers via copper catalyzed, ligand free-Ullmann reaction.
  • As a precursor for the preparation of silica xerogel which finds application in pharmaceutical drug carriers.
  • As a precursor for the synthesis of spherical silica particles by Stober process.


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Tato položka
33385913190387682
description

≥99.0% (GC)

description

99.999% trace metals basis

description

reagent grade, 98%

description

purum, ≥98.0% (GC)

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

assay

≥99.0% (GC)

assay

99.999% trace metals basis

assay

98%

assay

≥98.0% (GC)

technique(s)

GC/GC: suitable

technique(s)

-

technique(s)

-

technique(s)

-

form

liquid

form

liquid

form

liquid

form

liquid

vapor density

7.2 (vs air)

vapor density

7.2 (vs air)

vapor density

7.2 (vs air)

vapor density

5.25 (vs air)

bp

168 °C (lit.)

bp

168 °C (lit.)

bp

168 °C (lit.)

bp

121-122 °C (lit.)


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Piktogramy

FlameExclamation mark

Výstražné slovo

Warning

Kódy nebezpečí

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3

Cílové orgány

Respiratory system

Skladovací třída

3 - Flammable liquids

Bod vzplanutí (°F)

113.0 °F - closed cup

Bod vzplanutí (°C)

45 °C - closed cup

PPE (osobní ochranné prostředky)

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Seznamy omezení vyplývajících z předpisů

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78-10-4

CAS No.


Vyberte jednu z posledních verzí:

Osvědčení o analýze (COA)

Lot/Batch Number

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Questions

1–10 of 12 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What is the thermal conductivity of TEOS?

    1 answer
    1. Unfortunately, the thermal conductivity of this product is not determined.

      Helpful?

  4. What is the electrical conductivity or resistivity of TEOS

    1 answer
    1. This product is not tested for electrical conductivity. The compound is not expected to be a conductive material. The presence of TEOS in various coatings may impact the conductivity or resistivity of a given target compound, such as a metallic nanoparticle. See the links below to review articles that may be of interest:
      https://www.researchgate.net/figure/Effect-of-the-addition-of-TEOS-on-a-density-b-resistivity-c-residual-magnetic_fig5_371096514
      https://link.springer.com/article/10.1007/s12633-019-00180-y

      Helpful?

  5. According to the theise, TEOS was used in units of g. Do you sell powder or solid TEOS?

    1 answer
    1. Tetraethyl orthosilicate is only available in the liquid state. The melting point of the pure compound is -82.5 °C. The density of this material is 0.933 g/mL.
      See the link below to review the PubChem profile.
      https://pubchem.ncbi.nlm.nih.gov/compound/Tetraethyl-orthosilicate#section=Melting-Point

      Helpful?

  6. What is the vapor pressure of Tetraethyl orthosilicate (TEOS), Product No. 86578, at room temperature?

    1 answer
    1. The vapor pressure of TEOS at room temperature is 1.5 Torr.

      Helpful?

  7. How do you create a sol-gel with Tetraethyl orthosilicate (TEOS), Product No. 86578?

    1 answer
    1. TEOS can be polymerized with water; the polymerization is based on the hydrolysis or the Si-O-Et groups through forming networks linked by Si-O-Si groups.

      Helpful?

  8. How does the storage temperature relate to shipping conditions?

    1 answer
    1. The storage conditions that a Sigma-Aldrich catalog and label recommend for products are deliberately conservative. For many products, long-term storage at low temperatures will increase the time during which they are expected to remain in specification and therefore are labeled accordingly. Where short-term storage, shipping time frame, or exposure to conditions other than those recommended for long-term storage will not affect product quality, Sigma-Aldrich will ship at ambient temperature. The products sensitive to short-term exposure to conditions other than their recommended long-term storage are shipped on wet or dry ice. Ambient temperature shipping helps to control shipping costs for our customers. At any time, our customers can request wet- or dry-ice shipment, but the special handling is at customer expense if our product history indicates that the product is stable for regular shipment.

      Helpful?

  9. What type of applications can Product No. 86578, Tetraethyl orthosilicate (TEOS), be used in?

    1 answer
    1. TEOS can be used to synthesize sol-gels or aerogels.

      Helpful?

  10. What are the applications of sol-gels formed from Tetraethyl orthosilicate (TEOS), Product No. 86578?

    1 answer
    1. One of the most improtant application of the sol-gel process is the snythesis of zeolites. Other applications are optical ceramic materials or functionalized biosensors.

      Helpful?

1–10 of 12 Questions  

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