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For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
739103
Ru-MACHO®
solid
Akční nabídka
Synonyma:
Carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethyl]amino}ruthenium(II), {Bis[2-(diphenylphosphino)ethyl]amine}carboynlchlorohydridoruthenium(II)
Utratit 10 750 Kč – Ušetřit 5 %; Utratit 15 250 Kč – Ušetřit 10 %; Utratit 28 000 Kč – Ušetřit 15 %*
Přihlásit se pro ověření způsobilosti. Obchod s produkty
Vybrat velikost
| Vám/SKU | Dostupnost | Cena |
|---|---|---|
250 mg | Obraťte se na zákaznický servis a vyžádejte si informaci o dostupnosti. | 1 940,00 Kč |
1 g | Obraťte se na zákaznický servis a vyžádejte si informaci o dostupnosti. | 7 150,00 Kč |
5 g | Obraťte se na zákaznický servis a vyžádejte si informaci o dostupnosti. | 12 400,00 Kč |
O této položce
1 940,00 Kč
Ušetřete až 15 %
Název produktu
Ru-MACHO®,
form
solid
Quality Segment
reaction suitability
core: ruthenium, reagent type: catalyst
mp
260-290 °C
SMILES string
Cl[Ru].[C-]#[O+].C(CP(c1ccccc1)c2ccccc2)NCCP(c3ccccc3)c4ccccc4
InChI
1S/C28H29NP2.CO.ClH.Ru/c1-5-13-25(14-6-1)30(26-15-7-2-8-16-26)23-21-29-22-24-31(27-17-9-3-10-18-27)28-19-11-4-12-20-28;1-2;;/h1-20,29H,21-24H2;;1H;/q;;;+1/p-1
InChI key
GQFWSAKCCNATEV-UHFFFAOYSA-M
Application
<li><strong>Dehydrogenative Intramolecular Macrolactonization:</strong> Ru-MACHO catalyst is applied in dehydrogenative intramolecular macrolactonization of dihydroxy compounds, demonstrating its efficiency in organic synthesis with potential implications for pharmaceutical synthesis (Jamdade et al., 2022).</li>
<li><strong>Acceptorless Dehydrogenation of Methanol:</strong> Employing Ru-MACHO catalyst in the acceptorless dehydrogenation of methanol to produce carbon monoxide and hydrogen, this process highlights Ru-MACHO′s capability in catalytic transformations and green chemistry applications (Kaithal et al., 2021).</li>
<li><strong>Precapture and Hydrogenation of CO2:</strong> A study on the heterogenized Ru-MACHO catalytic systems for pre-capture and hydrogenation of CO2 into methanol, underscoring the catalyst′s potential in sustainable chemical processes (Szego et al., 2023).</li>
<li><strong>Pressure-dependent Hydrogenative Depolymerization:</strong> The Ru-MACHO catalyst is used for highly selective pressure-dependent hydrogenative depolymerization of polybutylene succinate, demonstrating the catalyst′s versatility in polymer processing and chemical recycling (Johnson et al., 2024).</li>
</ul>
Legal Information
1 of 1
Tato položka | |||
|---|---|---|---|
| description - | description - | description 95% | description certified reference material, pharmaceutical secondary standard |
| reaction suitability reagent type: catalyst, core: ruthenium | reaction suitability core: ruthenium, reagent type: catalyst | reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst | reaction suitability - |
| form solid | form solid | form solid | form - |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 300 |
| mp 260-290 °C | mp 128 °C (D) | mp 134-208 °C (MP data is all decomp.) | mp - |
Výstražné slovo
Warning
Kódy nebezpečí
Bezpečnostní pokyny
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Cílové orgány
Respiratory system
Skladovací třída
11 - Combustible Solids
Co se děje?
WGK 3
Bod vzplanutí (°F)
Not applicable
Bod vzplanutí (°C)
Not applicable
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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