736627

Mesitylcopper(I)

solid

• Synonyma: (2,4,6-Trimethylphenyl)copper
• Empirický vzorec (Hillův zápis): C₉H₁₁Cu
• Číslo CAS: 75732-01-3
• Molekulová hmotnost: 182.73
• UNSPSC Code: 12161600
• PubChem Substance ID: 329765125
• NACRES: NA.22
• MDL number: MFCD00015622

Vlastnosti

• Název produktu: Mesitylcopper(I),
• form: solid
• Quality Segment: 100
• reaction suitability: core: copper, reagent type: catalyst
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 184-191 °C
• greener alternative category: Aligned
• storage temp.: -10 to -25°C
• SMILES string: Cc1cc(C)c([Cu])c(C)c1
• InChI: 1S/C9H11.Cu/c1-7-4-8(2)6-9(3)5-7;/h4-5H,1-3H3;
• InChI key: BBUKMFLZOHNUQU-UHFFFAOYSA-N

Popis

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Mesitylcopper(I) is a thermally stable and highly soluble organocopper compound, which is commonly used as a metalation reagent in organic synthesis. In mixed lithium cuprate reagents, mesitylcopper serves as a useful ″holding group″. It is very sensitive to moisture and air therefore reactions must be carried out under anhydrous conditions.

Application

Mesitylcopper(I) is can be used to synthesize:

• Homo and heteroleptic copper(I) complexes such as Cu(I) alkoxides, siloxides, phosphates, amides, and phosphides.
• Biorelevant copper(I) complexes as biomimetic model compounds.
• Copper nanoparticles from stabilizing primary amines.

It can also be used as a selective mesityl group transfer reagent in stoichiometric C−C and C−heteroatom bond-forming reactions.

Bezpečnostní informace

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Skladovací třída: 11 - Combustible Solids
• flash_point_f: Not applicable
• flash_point_c: Not applicable