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693065

(R)-BINAP

Synonyma:

(R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene, (R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl, (R)-(+)-(1,1′-Binaphthalene-2,2′-diyl)bis(diphenylphosphine), (R)-(+)-BINAP

pro zobrazení organizačních a smluvních cen.

Vybrat velikost

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Vám/Skladová položkaDostupnostCena
100 mg
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851,00 Kč
638,25 Kč
500 mg
Obraťte se na zákaznický servis a vyžádejte si informaci o dostupnosti.
2 170,00 Kč

O této položce

Lineární vzorec:
[(C6H5)2PC10H6-]2
Číslo CAS:
Molekulová hmotnost:
622.67
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:

638,25 Kč

Ceníková cena851,00 KčUložit 25 %
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form

crystals

Quality Segment

optical activity

[α]20/D +222°, c = 0.5% in benzene

reaction suitability

reaction type: Asymmetric synthesis, reagent type: ligand
reaction type: Noyori Asymmetric Hydrogenation

mp

239-241 °C (lit.)

functional group

phosphine

SMILES string

c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8

InChI

1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H

InChI key

MUALRAIOVNYAIW-UHFFFAOYSA-N

Application

(R)-BINAP reacts with allylpalladium(II) chloride dimer to form a BINAP-palladium catalyst, which can catalyze the asymmetric allylation of 1,3-diketones to form chiral 2,2-dialkyl-1,3-diketones. It may also be used in the preparation of chirally stabilized rhodium nanoparticles, which can be used as a catalyst for the asymmetric hydroformylation of styrene and vinyl acetate.

Legal Information

Sold in collaboration with Takasago for research purposes only.

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Tato položka
69305769301496738
reaction suitability

reaction type: Asymmetric synthesis, reagent type: ligand
reaction type: Noyori Asymmetric Hydrogenation

reaction suitability

reaction type: Asymmetric synthesis, reagent type: ligand
reaction type: Noyori Asymmetric Hydrogenation

reaction suitability

reaction type: Asymmetric synthesis, reagent type: ligand
reaction type: Noyori Asymmetric Hydrogenation

reaction suitability

-

form

crystals

form

crystals

form

powder

form

crystals

functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

chloro, phosphine

mp

239-241 °C (lit.)

mp

238-240 °C (lit.)

mp

-

mp

-

optical activity

[α]20/D +222°, c = 0.5% in benzene

optical activity

[α]20/D -222, c = 0.5 in benzene

optical activity

-

optical activity

[α]/D +59±4°, c = 1% in chloroform

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100


Skladovací třída

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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Osvědčení o analýze (COA)

Lot/Batch Number

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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