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395056

Methylamine solution

greener alternative

2.0 M in THF

Methylamine solution

Synonyma:

Monomethylamine

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Vám/Skladová položkaDostupnostCena

O této položce

Lineární vzorec:
CH3NH2
Číslo CAS:
Molekulová hmotnost:
31.06
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
741851
Concentration:
2.0 M in THF
Form:
liquid
Informace o stanovených cenách a dostupnosti nejsou v současnosti dostupné.
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Quality Segment

vapor pressure

23.87 psi ( 55 °C), 7.24 psi ( 20 °C)

form

liquid

greener alternative product characteristics

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Learn more about the Principles of Green Chemistry.

sustainability

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concentration

2.0 M in THF

density

0.861 g/mL at 25 °C

functional group

amine

greener alternative category

SMILES string

CN

InChI

1S/CH5N/c1-2/h2H2,1H3

InChI key

BAVYZALUXZFZLV-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.
Methylamine (CH3NH2) is a simple aliphatic primary amine used as a chemical intermediate in organic synthesis. It is prominently used in the production of pesticides and solvents.

Application

Methylamine can be used as a reagent in the synthesis of the following:     
  • Methylmorpholine from diethylene glycol.       
  • N-methylalkylamines from oxoamines via formation of imine, followed by hydrogenation using Ni catalyst.   
  • N-Methyldipropylenetriamine by reacting with acrylonitrile, followed by hydrogenation.  
  • N-methyl hydroxypyrrolidines from chlorohydrin in the presence of NaCNBH as a reducing agent.[1]       
  • 2-(Methylamino)-6,7-dichloro-1,4-anthracenedione by reacting with 6,7-dichloro-1,4-anthracenedione.

Methylamine solution 2.0 M in THF can be used as a precursor that facilitates the synthesis of perovskite based materials. It can also be used as a deactivating agent to study the catalytic performance of acidic macroporous ion exchange resins. It can be annealed to reduce impurity in the grain boundaries, improve the stability and efficiency of the perovskite solar cells.[2]

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Tato položka
395048534102426466
concentration

2.0 M in THF

concentration

2.0 M in methanol

concentration

33 wt. % in absolute ethanol ((denatured with 1% toluene))

concentration

40 wt. % in H2O

form

liquid

form

liquid

form

-

form

-

density

0.861 g/mL at 25 °C

density

0.785 g/mL at 25 °C

density

0.756 g/mL at 25 °C

density

0.897 g/mL at 25 °C

vapor pressure

23.87 psi ( 55 °C), 7.24 psi ( 20 °C)

vapor pressure

10.86 psi ( 55 °C), 2.07 psi ( 20 °C)

vapor pressure

-

vapor pressure

280 mmHg ( 20 °C), 659 mmHg ( 40 °C)

functional group

amine

functional group

amine

functional group

amine

functional group

amine

greener alternative category

Enabling,

greener alternative category

Enabling,

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, Enabling

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-


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signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

Skladovací třída

3 - Flammable liquids

flash_point_f

<-29.2 °F - closed cup

flash_point_c

< -34 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


Seznamy omezení vyplývajících z předpisů

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109-99-9 + 74-89-5

CAS No.


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Osvědčení o analýze (COA)

Lot/Batch Number

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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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