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226149

tert-Butyldimethylsilyl trifluoromethanesulfonate

reagent grade, 98%

Synonyma:

TBDMS triflate, Trifluoromethanesulfonic acid tert-butyldimethylsilylester

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Vám/Skladová položkaDostupnostCena
1 g
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1 200,00 Kč
5 g
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2 610,00 Kč
1 957,50 Kč
25 g
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8 920,00 Kč

O této položce

Lineární vzorec:
CF3SO3Si(CH3)2C(CH3)3
Číslo CAS:
Molekulová hmotnost:
264.34
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
274-102-0
Beilstein/REAXYS Number:
2370068
MDL number:
Assay:
98%

1 200,00 Kč


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grade

reagent grade

Quality Segment

assay

98%

reaction suitability

reactivity: alcohol reactive, reagent type: protection reagent

refractive index

n20/D 1.385 (lit.)

bp

65-67 °C/12 mmHg (lit.)

density

1.151 g/mL at 25 °C (lit.)

functional group

fluoro, triflate

storage temp.

2-8°C

SMILES string

CC(C)(C)[Si](C)(C)OS(=O)(=O)C(F)(F)F

InChI

1S/C7H15F3O3SSi/c1-6(2,3)15(4,5)13-14(11,12)7(8,9)10/h1-5H3

InChI key

WLLIXJBWWFGEHT-UHFFFAOYSA-N

Application

This reagent was used to introduce a bulky tert-butyl dimethylsilyl group onto a cis-bis(alkenyl)oxirane facilitating a room temperature Cope rearrangement to a 2-CF3-4,5-dihydrooxepin.
Together with a thiolane promotes a rapid and efficient chalcogenide-Morita-Baylis-Hillman reaction.

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Tato položka
91741225649279471
description

reagent grade, 98%

description

purum, ≥98.0% (T)

description

99%

description

99%

assay

98%

assay

≥98.0% (T)

assay

99%

assay

99%

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

refractive index

n20/D 1.385 (lit.)

refractive index

n20/D 1.36 (lit.)

refractive index

n20/D 1.36 (lit.)

refractive index

n20/D 1.389 (lit.)

bp

65-67 °C/12 mmHg (lit.)

bp

77 °C/80 mmHg (lit.)

bp

77 °C/80 mmHg (lit.)

bp

85-86 °C/12 mmHg (lit.)

density

1.151 g/mL at 25 °C (lit.)

density

1.228 g/mL at 25 °C (lit.)

density

1.228 g/mL at 25 °C (lit.)

density

1.169 g/mL at 25 °C (lit.)

storage temp.

2-8°C

storage temp.

-

storage temp.

-

storage temp.

-


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signalword

Danger

Hazard Classifications

Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Skladovací třída

3 - Flammable liquids

wgk

WGK 3

flash_point_f

98.6 °F - closed cup

flash_point_c

37 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Osvědčení o analýze (COA)

Lot/Batch Number

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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