232491
5-Methoxyresorcinol
98%
Synonym(s):
3,5-Dihydroxyanisole, Phloroglucinol monomethyl ether
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About This Item
Linear Formula:
CH3OC6H3-1,3-(OH)2
CAS Number:
Molecular Weight:
140.14
Beilstein:
1423578
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
98%
bp
188-189 °C/12 mmHg (lit.)
mp
78-80 °C (lit.)
SMILES string
COc1cc(O)cc(O)c1
InChI
1S/C7H8O3/c1-10-7-3-5(8)2-6(9)4-7/h2-4,8-9H,1H3
InChI key
HDVRLUFGYQYLFJ-UHFFFAOYSA-N
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General description
Kinetics of the aroxyl radical-scavenging action of 5-methoxyresorcinol has been investigated. The kinetics of reaction of 5,7-diisopropyl-tocopheroxyl radical (Toc) with 5-methoxyresorcinol has been measured by stopped-flow spectrophotometer.
Application
5-Methoxyresorcinol was used in synthesis of:
- isorobustin
- substituted linear and angular benzofurocoumarins
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Total synthesis of isorobustin.
Barton DHR, et al.
Tetrahedron Letters, 31(51), 7449-7452 (1990)
Kazuo Mukai et al.
Free radical biology & medicine, 38(9), 1243-1256 (2005-04-06)
The reaction rates (k(r)) of 5,7-diisopropyl-tocopheroxyl radical (Toc) with catechins (epicatechin (EC), epicatechin gallate (ECG), epigallocatechin (EGC), epigallocatechin gallate (EGCG)) and related compounds (methyl gallate (MG), 4-methylcatechol (MC), and 5-methoxyresorcinol (MR)) have been measured by stopped-flow spectrophotometer. The k(r) values
Synthesis of linear and angular benzofurocoumarins.
Teran C, et al.
Synthesis, 1997(12), 1384-1386 (1997)
Shuji Mitani et al.
Journal of agricultural and food chemistry, 56(12), 4406-4417 (2008-05-27)
Kinetic study of the aroxyl radical-scavenging action of catechins (epicatechin (EC), epicatechin gallate (ECG), epigallocatechin (EGC), and epigallocatechin gallate (EGCG)) and related compounds (methyl gallate (MG), 4-methylcatechol (MC), and 5-methoxyresorcinol (MR)) has been performed. The second-order rate constant ( k
J U Kreft et al.
European journal of biochemistry, 226(3), 945-951 (1994-12-15)
The previously studied complete methyl transfer sequence of tetrahydrofolate-dependent O-demethylation catalyzed by Holophaga foetida strain TMBS4 extracts was separated into two steps using cobalamins as non-physiological substrates: electrochemically produced cob(I) alamin served as methyl acceptor for phenyl methyl ether demethylation
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