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Merck

33120

Sigma-Aldrich

N,N-Dimetilformamida

puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99.8% (GC)

Sinónimos:

DMF, NSC 5356

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About This Item

Fórmula lineal:
HCON(CH3)2
Número de CAS:
Peso molecular:
73.09
Beilstein:
605365
Número CE:
Número MDL:
Código UNSPSC:
12352111
ID de la sustancia en PubChem:
NACRES:
NA.21
Ensayo:
≥99.8% (GC)
bp:
152-154 °C
153 °C (lit.)
presión de vapor:
2.7 mmHg ( 20 °C)

grado

ACS reagent
puriss. p.a.

Nivel de calidad

Agency

reag. Ph. Eur.

densidad de vapor

2.5 (vs air)

presión de vapor

2.7 mmHg ( 20 °C)

Ensayo

≥99.8% (GC)

Formulario

liquid

temp. de autoignición

833 °F

lim. expl.

15.2 %

impurezas

≤0.003% free acid (as CH3COOH)
≤0.005% free alkali (as NH3)
≤0.005% non-volatile matter
≤0.1% water (Karl Fischer)

color

APHA: ≤15

índice de refracción

n20/D 1.4290-1.4310
n20/D 1.430 (lit.)

pH

7 (20 °C, 200 g/L)

bp

152-154 °C
153 °C (lit.)

mp

−61 °C (lit.)

densidad

0.948-0.950 g/mL at 20 °C
0.944 g/mL (lit.)

trazas de catión

Al: ≤0.5 mg/kg
B: ≤0.02 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.5 mg/kg
Li: ≥0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤1 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sn: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

cadena SMILES

[H]C(=O)N(C)C

InChI

1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3

Clave InChI

ZMXDDKWLCZADIW-UHFFFAOYSA-N

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Descripción general

N,N-Dimethylformamide (DMF) is commonly employed as a solvent for various organic reactions. DMF is a useful solvent employed for the isolation of chlorophyll from plant tissues. It is widely employed reagent in organic synthesis. It plays multiple roles in various reactions such as solvent, dehydrating agent, reducing agent as well as catalyst. It is a multipurpose building block for the synthesis of compounds containing O, -CO, -NMe2, -CONMe2, -Me, -CHO as functional groups.

Aplicación

Disolvente para muchos compuestos orgánicos hidrófobos.
N,N-Dimethylformamide (DMF) may be employed as a solvent in the following studies:
  • Extraction of chlorophyll containing pigments from the intact tissues of cotyledons of Cucumis sativus.
  • Isolation of chlorophyll a from the cell cultures of unicellular marine algae.4
  • As reducing agent and solvent for the preparation of Au@Ag core-shell nanocrystals.

Envase

2.5 L also available in PE-bottles

Otras notas

The article number 33120-4X2.5L-M will be discontinued. Please order the single bottle 33120-2.5L-M which is physically identical with the same exact specifications.
The article number 33120-4X2.5L-R will be discontinued. Please order the single bottle 33120-2.5L-R which is physically identical with the same exact specifications.
The article number 33120-6X1L-M will be discontinued. Please order the single bottle 33120-1L-M which is physically identical with the same exact specifications.
The article number 33120-6X1L-R will be discontinued. Please order the single bottle 33120-1L-R which is physically identical with the same exact specifications.

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Palabra de señalización

Danger

Clasificaciones de peligro

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

135.5 °F - closed cup

Punto de inflamabilidad (°C)

57.5 °C - closed cup


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Shape-dependent evolution of Au@ Ag core- shell nanocrystals by PVP-assisted N,N-dimethylformamide reduction.
Tsuji M, et al.
Crystal Growth & Design, 8(7), 2528-2536 (2008)
R Moran et al.
Plant physiology, 65(3), 478-479 (1980-03-01)
Photosynthetic pigments from etiolated cucumber (Cucumis sativus var. Beit Alpha improved, Hazera Co., Gedera) cotyledons were extracted by direct immersion of the intact cotyledons into the solvent N,N-dimethylformamide (DMF). The solvent is especially efficient when pigment concentration is low; time
W P Inskeep et al.
Plant physiology, 77(2), 483-485 (1985-02-01)
We found inconsistencies in the commonly used data for chlorophyll analysis in 80% acetone. Recently developed extinction coefficients for chlorophyll b in N,N-dimethylformamide (DMF) based on values from 80% acetone are low as a result of these inconsistencies. We determined
Kun Liu et al.
Nanoscale, 4(20), 6574-6580 (2012-09-15)
Studies on the self-assembly of metal nanoparticles (NPs) in the presence of ions are motivated by the biosensing applications of NP clusters and the capability to control the morphology of clusters of oppositely charged NPs. The effect of ions has
S Ollier et al.
Journal of dairy science, 97(8), 4942-4954 (2014-06-03)
A cow's risk of acquiring a new intramammary infection during the dry period increases with milk production at drying off and decreases as mammary gland involution progresses. A method commonly used to reduce milk production is a drastic reduction in

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