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Merck

60153

Sigma-Aldrich

Potassium citrate tribasic monohydrate

purum p.a., ≥99.0% (NT)

Sinónimos:

Citric acid tripotassium salt, Tripotassium citrate

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About This Item

Fórmula lineal:
HOC(COOK)(CH2COOK)2 · H2O
Número de CAS:
Peso molecular:
324.41
Beilstein/REAXYS Number:
3924344
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21

grade

purum p.a.

Quality Level

assay

≥99.0% (NT)

form

liquid

pH

7.5-9.0 (25 °C, 50 mg/mL in H2O)

mp

275 °C (dec.) (lit.)

solubility

H2O: 0.5 g/10 mL, clear, colorless

anion traces

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
Na: ≤1500 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

SMILES string

O.[K+].[K+].[K+].OC(CC([O-])=O)(CC([O-])=O)C([O-])=O

InChI

1S/C6H8O7.3K.H2O/c7-3(8)1-6(13,5(11)12)2-4(9)10;;;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;;;1H2/q;3*+1;/p-3

InChI key

PJAHUDTUZRZBKM-UHFFFAOYSA-K

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General description

Potassium citrate tribasic monohydrate is the tripotassium salt of citric acid. It has been proposed as a promising organic salt for the formation of aqueous two-phase system (ATPS). UCON (temperature-responsive polymer) + potassium citrate ATPS has been studied.

Application

Potassium citrate tribasic monohydrate (tribasic potassium citrate) may be added as a promoter during the preparation of activated carbon-supported CuCl2 + PdCl2 + NaOH catalyst. This catalyst was employed for the conversion of ethanol to diethyl carbonate (DEC).1 It may be used to compose the fermentation medium for Aspergillus niger 72-4. It may be used as a standard to investigate the influence of Bergenia ligulata rhizome (BLR) on CaC2O4 crystallization.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Carbon dioxide fixation by cell-free extracts of Aspergillus niger.
Woronick CL and Johnson MJ.
The Journal of Biological Chemistry, 235(1), 9-15 (1960)
(Liquid+ liquid) equilibria of polymer-salt aqueous two-phase systems for laccase partitioning: UCON 50-HB-5100 with potassium citrate and (sodium or potassium) formate at 23?C.
Lladosa E, et al.
The Journal of Chemical Thermodynamics, 55, 166-171 (2012)
Antiurolithic effect of Bergenia ligulata rhizome: an explanation of the underlying mechanisms.
Bashir S and Gilani AH.
Journal of Ethnopharmacology, 122(1), 106-116 (2009)
Clay Mechlin et al.
Journal of endourology, 25(9), 1541-1545 (2011-08-06)
Oral citrate supplements have been shown to decrease kidney stone recurrence rates in both laboratory and clinical studies. The taste of the citrate supplements, however, is poor, and long-term compliance is low. Our objective was to determine if Splenda(®) added
Kendall F Moseley et al.
Journal of bone and mineral research : the official journal of the American Society for Bone and Mineral Research, 28(3), 497-504 (2012-09-20)
The dietary acid load created by the typical Western diet may adversely impact the skeleton by disrupting calcium metabolism. Whether neutralizing dietary acid with alkaline potassium salts results in sustained improvements in calcium balance remains controversial. In this randomized, double-blind

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